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Merck
CN

112771

异硫氰酸甲酯

97%

别名:

Isothiocyanatomethane, Isothiocyanic acid methyl ester

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线性分子式:
CH3NCS
化学文摘社编号:
分子量:
73.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-132-5
Beilstein/REAXYS Number:
605319
MDL number:
Assay:
97%
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assay

97%

InChI key

LGDSHSYDSCRFAB-UHFFFAOYSA-N

InChI

1S/C2H3NS/c1-3-2-4/h1H3

SMILES string

CN=C=S

vapor pressure

21 mmHg ( 20 °C)

bp

117-118 °C (lit.)

mp

30-34 °C (lit.)

solubility

H2O: slightly soluble

density

1.069 g/cm3 at 25 °C (lit.)

functional group

amine, isothiocyanate

Quality Level

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General description

异硫氰酸甲酯(MITC)是一种常见的土壤熏蒸剂副产品,具有毒性和腐蚀性,对皮肤和呼吸道有刺激作用。它可以通过自由基反应降解并从受污染的水中去除。†.

异硫氰酸甲酯是一种活性化合物,可用作葡萄酒中的抗发酵剂,也可用作有效的杀虫剂。

Application

异硫氰酸甲酯可用于:
  • 氨基酸序列分析
  • 研究农药威百亩(异硫氰酸甲酯为其活性成分)对河岸微生物群落的影响 。

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

86.0 °F - closed cup

flash_point_c

30 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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分析证书(COA)

Lot/Batch Number

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Bio-inspired ultrasensitive colorimetric detection of methyl isothiocyanate on nylon-6 nanofibrous membrane: A comparison of biological thiol reactivities
Peixin T et al.
Journal of Hazardous Materials, 362, 375-382 (2019)
Microbial ecology, toxicology and chemical fate of methyl isothiocyanate in riparian soils from the upper Sacramento river.
Environmental Toxicology and Chemistry / Setac, 15(10), 1694-1701 (1996)
Michael L Dourson et al.
Regulatory toxicology and pharmacology : RTP, 58(2), 181-188 (2010-04-22)
The preplant fumigants, metam-sodium, metam-potassium, and dazomet undergo decomposition to the biocide methyl isothiocyanate (MITC) in moist soils. Since MITC vapor can migrate from its site of application, we developed an estimate of health protective concentrations for airborne exposures to
Luis O Ruzo
Pest management science, 62(2), 99-113 (2005-11-26)
Production and use of methyl bromide, a soil fumigant, are being restricted because of this chemical's deleterious effects on stratospheric ozone concentrations. Several products, some of which are currently used as soil fumigants, are being considered as possible replacements for
Y Zhang et al.
Journal of environmental quality, 34(5), 1566-1572 (2005-08-11)
Recent studies have observed enhanced degradation of methyl isothiocyanate (MITC) from repeated fumigation in agricultural soils. Little is known about fumigant degradation in forest and nursery soils. This study was conducted to determine degradation rates of MITC and chloropicrin (CP)

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