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114081

4-(苄氧基)氯苄

Name: 4-(苄氧基)氯苄
Brand: ALDRICH

97%

别名:

4-氯甲基-α-苯基苯甲醚

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关于此项目

线性分子式:

C₆H₅CH₂OC₆H₄CH₂Cl

化学文摘社编号:

836-42-0

分子量:

232.71

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847156

EC Number:

212-648-3

Beilstein/REAXYS Number:

882526

MDL number:

MFCD00000916

Assay:

97%

Form:

solid

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属性

Quality Level

200

assay

97%

form

solid

mp

77-79 °C (lit.)

functional group

chloro, phenyl

storage temp.

2-8°C

SMILES string

ClCc1ccc(OCc2ccccc2)cc1

InChI

1S/C14H13ClO/c15-10-12-6-8-14(9-7-12)16-11-13-4-2-1-3-5-13/h1-9H,10-11H2

InChI key

UYQPSKUPEXAQRJ-UHFFFAOYSA-N

说明

General description

4-(Benzyloxy)benzyl chloride acts as a solid support to readily determine the loading of the corresponding polymer-bound acids by direct cleavage. This was determined while studying the coupling of substituted aromatic, heterocyclic, and alkyl carboxylates to the resin.

Application

4-(benzyloxy)benzyl chloride is used in the preparation of 4-aryl-3,4-dihydropyrimidine-5-carboxylates (DHPMs) which exhibits a wide spectrum of biological effects.

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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High-Speed Couplings and Cleavages in Microwave-Heated, Solid-Phase Reactions at High Temperatures.

The Journal of Organic Chemistry, 2001(5), 919-925 (2001)

Highly versatile solid phase synthesis of biofunctional 4-aryl-3,4-dihydropyrimidines using resin-bound isothiourea building blocks and multidirectional resin cleavage.

C O Kappe

Bioorganic & medicinal chemistry letters, 10(1), 49-51 (2000-01-15)

A series of pharmacologically active, functionalized 4-aryl-3,4-dihydropyrimidine-5-carboxylates (DHPMs) are prepared by a versatile novel solid phase approach. In the key step, a polymer-bound thiouronium salt is condensed with unsaturated 1-ketoesters. The resulting polymer bound 1,4-dihydropyrimidines are cleaved from the resin

A novel phenolic propanediamine moiety-based lung-targeting therapy for asthma.

Jianbo Li et al.

Drug delivery, 25(1), 1117-1126 (2018-05-22)

Asthma is one of the most prevalent chronic inflammatory diseases of lung. Current asthma therapy using inhaled corticosteroid often results in undesired treatment outcome due to poor compliance and drugs' lack of tissue specificity. N,N,N'-trimethyl-N'-(2-hydroxyl-3-methyl-5-123Iiodobenzyl)-1,3-propanediamine (HIPD), a phenolic propanediamine derivative

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全球贸易项目编号

货号	GTIN
114081-25G	04061832278308
114081-5G	04061832278315