115126
10-十一烯酸甲酯
96%
别名:
10-十一烯酸甲基酯, 十一碳烯酸甲酯
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关于此项目
线性分子式:
CH2=CH(CH2)8CO2CH3
化学文摘社编号:
分子量:
198.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-910-8
MDL number:
InChI key
KISVAASFGZJBCY-UHFFFAOYSA-N
InChI
1S/C12H22O2/c1-3-4-5-6-7-8-9-10-11-12(13)14-2/h3H,1,4-11H2,2H3
SMILES string
COC(=O)CCCCCCCCC=C
assay
96%
refractive index
n20/D 1.437 (lit.)
bp
245 °C (lit.)
density
0.882 g/mL at 25 °C (lit.)
functional group
allyl, ester
Quality Level
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General description
10-十一碳烯酸甲酯是长链脂族 α,ω-二烯通过无环二烯复分解（ADMET）聚合的链终止剂。这有助于将所得聚酯的分子量控制在 10 至 45kDa 的范围内。
Application
10-十一碳烯酸甲酯是不饱和脂肪酸酯，作为反应底物可用于：
- 经氢甲酰化反应制备双功能聚合物前体。
- 在钯催化剂存在下，经胺基羰基化反应合成α,ω-酯酰胺。
- 用于改性商用有机硅单体1,3,5,7-四甲基环四硅氧烷，用于在水中通过氢化硅烷化反应制备有机硅空心纳米/微结构。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
239.0 °F - closed cup
flash_point_c
115 °C - closed cup
ppe
Eyeshields, Gloves
Silicone Nano/Microstructures Obtained in Ionic Polymerization.
Kuzmicz D, et al.
Macromolecular Symposia, 308(1), 43-48 (2011)
Silicone nano/microstructures obtained in ionic polymerization
Macromolecular Symposia, 308(1), 43-48 (2011)
Anastasiya Rybak et al.
ChemSusChem, 1(6), 542-547 (2008-08-15)
The preparation of a long-chain aliphatic alpha,omega-diene from plant oil derivatives and its subsequent polymerization through acyclic diene metathesis (ADMET) is described. The ADMET bulk polymerization of the thus-obtained monomer, undecyl undecenoate, was investigated and optimized by applying ruthenium-based metathesis
Selective formation of ?,?-ester amides from the aminocarbonylation of castor oil derived methyl 10-undecenoate and other unsaturated substrates
Jimenez-Rodriguez C, et al.
Catalysis Science & Technology, 4(8), 2332-2339 (2014)
Improvement of Productivity for Aqueous Biphasic Hydroformylation of Methyl 10-Undecenoate: A Detailed Phase Investigation
Bianga J, et al.
European Journal of Lipid Science and Technology, 122(1), 1900317-1900317 (2020)
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