116025
扁桃腈
technical grade
别名:
α-氰基苄醇, 杏仁腈, 苯甲氰醇
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关于此项目
线性分子式:
C6H5CH(OH)CN
化学文摘社编号:
分子量:
133.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-532-7
Beilstein/REAXYS Number:
2207122
MDL number:
InChI key
NNICRUQPODTGRU-UHFFFAOYSA-N
InChI
1S/C8H7NO/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8,10H
SMILES string
OC(C#N)c1ccccc1
grade
technical grade
bp
170 °C (lit.)
solubility
alcohol: freely soluble, chloroform: freely soluble, diethyl ether: freely soluble
density
1.117 g/mL at 25 °C (lit.)
functional group
hydroxyl, nitrile, phenyl
Application
Mandelonitrile has been used to extract mandeloamide by the nitrilase variants.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
206.6 °F - closed cup
flash_point_c
97 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
D H Sreenivasa Rao et al.
Applied biochemistry and biotechnology, 193(2), 560-576 (2020-10-13)
Enantiopure β-nitroalcohols are versatile intermediates used in the synthesis of important pharmaceuticals and chiral synthons. In this article, immobilized Arabidopsis thaliana HNL (AtHNL)-catalyzed preparation of (S)-β-nitroalcohols from their racemic mixtures via retro-Henry reaction was studied. AtHNL used in biocatalysis was
Diana Uhrich et al.
Frontiers in microbiology, 8, 2111-2111 (2017-11-25)
The preparation and characterization of UV-cured polyurethane-based materials for the mild inclusion immobilization of enzymes was investigated. Full curing of the polymer precursor/enzyme solution mixture was realized by a short irradiation with UV-light at ambient temperatures. The included aqueous enzyme
Laboratory evolved biocatalysts for stereoselective syntheses of substituted benzaldehyde cyanohydrins.
Zhibin Liu et al.
Chembiochem : a European journal of chemical biology, 9(1), 58-61 (2007-12-07)
A biocatalytic Henry reaction--the hydroxynitrile lyase from Hevea brasiliensis also catalyzes nitroaldol reactions.
Thomas Purkarthofer et al.
Angewandte Chemie (International ed. in English), 45(21), 3454-3456 (2006-04-25)
Zhi-Jun Zhang et al.
Bioprocess and biosystems engineering, 34(3), 315-322 (2010-10-21)
A nitrilase gene from Alcaligenes sp. ECU0401 was cloned and overexpressed in Escherichia coli BL21 (DE3) in a soluble form. The encoded protein with a His₆-tag was purified to nearly homogeneity as revealed by SDS-PAGE with a molecular weight of
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