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117722

1-金刚烷甲酰氯

95%

别名:

1-Adamantanecarboxylic acid chloride, 1-Chlorocarbonyladamantane

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关于此项目

经验公式（希尔记法）:
C11H15ClO
化学文摘社编号:
2094-72-6
分子量:
198.69
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24847343
EC Number:
218-252-7
Beilstein/REAXYS Number:
389960
MDL number:
MFCD00074724
Assay:
95%
Form:
solid
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Quality Level

200

assay

95%

form

solid

bp

135-136 °C/10 mmHg (lit.)

mp

49-51 °C (lit.)

functional group

acyl chloride

SMILES string

ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2

InChI

1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11-

InChI key

MIBQYWIOHFTKHD-KJZNFTALSA-N

General description

1-金刚烷羰基氯与异丙基亚磷酸三乙胺反应生成混合酸酐，这是一种用于氢-膦酸盐 DNA 合成的有效封端试剂 。它是金属铟存在下苯甲醚 Friedel–Crafts 酰化反应的良好底物 。

Application

1-金刚烷羰基氯被用于制备高效的胺修饰的寡脱氧核苷酸，用于制备 DNA 微阵列 。

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH014

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCC7100
BCCC6498
BCCC6499
BCCC4876
BCBP3427V

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Nagendra Kumar Kamisetty et al.
Analytical and bioanalytical chemistry, 387(6), 2027-2035 (2007-01-24)
Amine-modified oligodeoxynucleotides (AMO) are commonly used probe oligodeoxynucleotides for DNA microarray preparation. Two methods are currently used for AMO preparation--use of amine phosphoramidites protected by acid-labile monomethoxytrityl (MMT) groups or alkali-labile trifluoroacetyl (TFA) groups. Because conventional AMO preparation procedures have
Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal.
Jang DO, et al.
Tetrahedron Letters, 47(34), 6063-6066 (2006)
Anna K Blakney et al.
Biomacromolecules, 21(6), 2482-2492 (2020-04-07)
Messenger RNA (mRNA) is a promising platform for both vaccines and therapeutics, and self-amplifying RNA (saRNA) is particularly advantageous, as it enables higher protein expression and dose minimization. Here, we present a delivery platform for targeted delivery of saRNA using
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全球贸易项目编号

货号GTIN
117722-25G04061838705310
117722-5G04061838705327