Merck
CN
所有图片(1)

文件

120847

Sigma-Aldrich

邻氟苯甲酰氯

99%

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线性分子式:
FC6H4COCl
CAS号:
393-52-2
分子量:
158.56
Beilstein:
636864
EC 号:
206-887-2
MDL编号:
MFCD00000656
PubChem化学物质编号:
24847433
NACRES:
NA.22

质量水平

200

检测方案

99%

折射率

n20/D 1.536 (lit.)

bp

90-92 °C/15 mmHg (lit.)

mp

4 °C (lit.)

密度

1.328 g/mL at 25 °C (lit.)

SMILES string

Fc1ccccc1C(Cl)=O

InChI

1S/C7H4ClFO/c8-7(10)5-3-1-2-4-6(5)9/h1-4H

InChI key

RAAGZOYMEQDCTD-UHFFFAOYSA-N

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相关类别

一般描述

2-Fluorobenzoyl chloride reacts with ethyl 5-amino-1-methylpyrazole-4-carboxylate to give N-mono-N,N-di-substituted intermediate which on ring closure yields heteroannulated oxazinone.

应用

2-Fluorobenzoyl chloride has been used in the preparation of 3-(N-Hydroxycarbamimidoyl)-benzoic acid methyl ester. It has been used to develop an hollow-fiber liquid phase microextraction with in situ derivatization method coupled with HPLC-UV for the determination of metformin hydrochloride in biological fluids.

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

251.6 °F - closed cup

闪点(°C)

122 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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P Jakobsen et al.
Bioorganic & medicinal chemistry, 8(12), 2803-2812 (2000-12-29)
The synthesis of a series of 2-aryl substituted hetero annulated 1,3-oxazin-4-ones and their evaluation as specific inhibitors of the tissue factor (TF)/factor VIIa (FVIIa)-induced pathway of coagulation is reported. Inhibitory activities (IC50 values) in the range 0.64 to > 40
Lulin Zhou et al.
Magnetic resonance in chemistry : MRC, 54(3), 222-226 (2015-11-03)
A new method utilization of NMR spectra was developed for structural and quantitative analysis of enol forms of acetylacetone and ethyl acetoacetate. Acetylacetone and ethyl acetoacetate were determined by (19) F NMR upon derivatisation with р-fluorobenzoyl chloride. The base-catalyzed derivatives
Gazala Mohamed Ben-Hander et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 941, 123-130 (2013-11-10)
A three phase hollow fiber liquid-phase microextraction with in situ derivatization (in situ HF-LPME) followed by high-performance liquid chromatography-ultraviolet detection (HPLC-UV) method was developed for the trace determination of metformin hydrochloride (MH) in biological fluids. A new derivatization agent pentafluorobenzoyl
Dima A Sabbah et al.
Medicinal chemistry (Shariqah (United Arab Emirates)), 15(4), 417-429 (2018-09-13)
Phosphoinositide 3-kinase α (PI3Kα) has emerged as a promising target for anticancer drug design. Target compounds were designed to investigate the effect of the p-OCH3 motifs on ligand/PI3Kα complex interaction and antiproliferative activity. Synthesis of the proposed compounds, biological examination
Sara Gonzalez-Hilarion et al.
Orphanet journal of rare diseases, 7, 58-58 (2012-09-04)
Nonsense mutations are at the origin of many cancers and inherited genetic diseases. The consequence of nonsense mutations is often the absence of mutant gene expression due to the activation of an mRNA surveillance mechanism called nonsense-mediated mRNA decay (NMD).

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