122130
3,5-二溴水杨醛
98%
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关于此项目
线性分子式:
Br2C6H2-2-(OH)CHO
化学文摘社编号:
分子量:
279.91
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-003-4
MDL number:
Assay:
98%
Form:
solid
产品名称
3,5-二溴水杨醛, 98%
InChI key
JHZOXYGFQMROFJ-UHFFFAOYSA-N
InChI
1S/C7H4Br2O2/c8-5-1-4(3-10)7(11)6(9)2-5/h1-3,11H
SMILES string
Oc1c(Br)cc(Br)cc1C=O
assay
98%
form
solid
mp
82-83.5 °C (lit.)
solubility
methanol: soluble 25 mg/mL, clear, yellow to brown
functional group
aldehyde
bromo
Quality Level
Application
3,5-Dibromosalicylaldehyde was used in the synthesis of Schiff base, 15N-Labeled N-(3,5-dibromosalicylidene)-methylamine. It was used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).
General description
3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Haibo Ni et al.
Experimental neurology, 304, 102-113 (2018-03-09)
Receptor for activated protein kinase C 1 (RACK1) is a multifaceted scaffolding protein known to be involved in the regulation of signaling events required for neuronal protection. In the present study, we investigated the role of RACK1 in secondary brain
Shasad Sharif et al.
Journal of the American Chemical Society, 128(10), 3375-3387 (2006-03-09)
The tautomeric equilibrium in a Schiff base, N-(3,5-dibromosalicylidene)-methylamine 1, a model for the hydrogen bonded structure of the cofactor pyridoxal-5'-phosphate PLP which is located in the active site of the enzyme, was measured by means of 1H and 15N NMR
Z Rozwadowski
Magnetic resonance in chemistry : MRC, 44(9), 881-886 (2006-06-03)
Deuterium isotope effects on 13C chemical shift of tetrabutylammonium salts of Schiff bases, derivatives of amino acids (glycine, L-alanine, L-phenylalanine, L-valine, L-leucine, L-isoleucine and L-methionine) and various ortho-hydroxyaldehydes in CDCl3 have been measured. The results have shown that the tetrabutylammonium
[Colorimetric determination of 4-chloro-2-(o-chlorobenzoyl)-N-methyl-N alpha-glycylglycinanilide with 3,5-dibromsalicyladehyde (author's transl)].
R Ikenishi et al.
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 101(6), 532-537 (1981-06-01)
Nazanin Kordestani et al.
Dalton transactions (Cambridge, England : 2003), 49(24), 8247-8264 (2020-06-09)
The enantiopure Schiff bases (R or S)-N-1-(phenyl)ethyl-2,4-X1,X2-salicylaldimine (X1, X2 = Cl, Br, I) coordinate to copper(ii) and provide pseudotetrahedral bis[(S or R)-N-1-(phenyl)ethyl-(2,4-X1,X2-salicylaldiminato-κ2N,O)]-Δ/Λ-Cu(ii) (Λ/Δ-Cu-R or Δ/Λ-Cu-S). An induced Λ and Δ-chirality at-metal centre has been launched along the C2-axis of the
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