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Merck
CN

122130

3,5-二溴水杨醛

98%

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关于此项目

线性分子式:
Br2C6H2-2-(OH)CHO
化学文摘社编号:
分子量:
279.91
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-003-4
MDL number:
Assay:
98%
Form:
solid
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Quality Level

assay

98%

form

solid

mp

82-83.5 °C (lit.)

solubility

methanol: soluble 25 mg/mL, clear, yellow to brown

functional group

aldehyde, bromo

SMILES string

Oc1c(Br)cc(Br)cc1C=O

InChI

1S/C7H4Br2O2/c8-5-1-4(3-10)7(11)6(9)2-5/h1-3,11H

InChI key

JHZOXYGFQMROFJ-UHFFFAOYSA-N

General description

3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.

Application

3,5-Dibromosalicylaldehyde was used in the synthesis of Schiff base, 15N-Labeled N-(3,5-dibromosalicylidene)-methylamine. It was used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).


pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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[Colorimetric determination of 4-chloro-2-(o-chlorobenzoyl)-N-methyl-N alpha-glycylglycinanilide with 3,5-dibromsalicyladehyde (author's transl)].
R Ikenishi et al.
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 101(6), 532-537 (1981-06-01)
Haibo Ni et al.
Experimental neurology, 304, 102-113 (2018-03-09)
Receptor for activated protein kinase C 1 (RACK1) is a multifaceted scaffolding protein known to be involved in the regulation of signaling events required for neuronal protection. In the present study, we investigated the role of RACK1 in secondary brain
Shasad Sharif et al.
Journal of the American Chemical Society, 128(10), 3375-3387 (2006-03-09)
The tautomeric equilibrium in a Schiff base, N-(3,5-dibromosalicylidene)-methylamine 1, a model for the hydrogen bonded structure of the cofactor pyridoxal-5'-phosphate PLP which is located in the active site of the enzyme, was measured by means of 1H and 15N NMR



全球贸易项目编号

货号GTIN
122130-10G04061835048397