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122459

二茂铁甲醛

Name: 二茂铁甲醛
Brand: ALDRICH

98%, solid

别名:

环戊二烯基(甲酰基环戊二烯基)铁

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关于此项目

经验公式（希尔记法）:

C₁₁H₁₀FeO

化学文摘社编号:

12093-10-6

分子量:

214.04

NACRES:

NA.22

PubChem Substance ID:

24847489

UNSPSC Code:

12352300

EC Number:

235-158-1

MDL number:

MFCD00001429

Assay:

98%

Form:

solid

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属性

产品名称

二茂铁甲醛, 98%

Quality Level

100

assay

98%

form

solid

reaction suitability

core: iron, reagent type: catalyst

mp

118-120 °C (lit.)

functional group

aldehyde

storage temp.

2-8°C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.[H]C(=O)[C]2[CH][CH][CH][CH]2

InChI

1S/C6H5O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-5H;1-5H;

InChI key

UQTCQJVPLIVCAX-UHFFFAOYSA-N

说明

Application

用于制备选择性亚甲胺叶立德环加成反应所用的手性二茂铁氮丙啶基甲醇。

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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Preparation and redox-controlled reversible response of ferrocene-modified poly(allylamine hydrochloride) microcapsules.

Zhipeng Wang et al.

Langmuir : the ACS journal of surfaces and colloids, 27(4), 1286-1291 (2010-11-04)

Single-component microcapsules were fabricated by the in situ reaction of ferrocenecarboxaldehyde (Fc-CHO) with poly(allylamine hydrochloride) (PAH) doped inside CaCO(3) microparticles, followed by core removal. The PAH-Fc microcapsules had very thick shells with remnant PAH-Fc inside, leading to a robust capsule

Structural and biological investigation of ferrocene-substituted 3-methylidene-1,3-dihydro-2H-indol-2-ones.

John Spencer et al.

Dalton transactions (Cambridge, England : 2003), (6)(6), 918-921 (2009-01-29)

The Knoevenagel condensation of 1,3-dihydro-2H-indol-2-one with ferrocene carboxaldehyde afforded an approximate 2:1 mixture of the geometrical isomers (E)- and (Z)-3-ferrocenylmethylidene-1,3-dihydro-2H-indol-2-one respectively in an overall 67% yield; the air and solution-stable isomers were readily separated by preparative thin layer chromatography and

Antileishmanial activity of quinazoline derivatives: synthesis, docking screens, molecular dynamic simulations and electrochemical studies.

Cesar Mendoza-Martínez et al.

European journal of medicinal chemistry, 92, 314-331 (2015-01-13)

A series of quinazoline-2,4,6-triamine were synthesized and evaluated in vitro against Leishmania mexicana. Among them, N(6)-(ferrocenmethyl)quinazolin-2,4,6-triamine (H2) showed activity on promastigotes and intracellular amastigotes, as well as low cytotoxicity in mammalian cells. Docking and electrochemical studies showed the importance of both

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全球贸易项目编号

货号	GTIN
122459-5G	04061838721259
122459-25G	04061838721242