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Merck
CN

122858

2-氨基-5-溴吡啶

97%

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经验公式(希尔记法):
C5H5BrN2
化学文摘社编号:
分子量:
173.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-019-9
Beilstein/REAXYS Number:
108737
MDL number:
Assay:
97%
Form:
solid
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产品名称

2-氨基-5-溴吡啶, 97%

InChI key

WGOLHUGPTDEKCF-UHFFFAOYSA-N

InChI

1S/C5H5BrN2/c6-4-1-2-5(7)8-3-4/h1-3H,(H2,7,8)

SMILES string

Nc1ccc(Br)cn1

assay

97%

form

solid

mp

133-138 °C (lit.)

functional group

bromo

Quality Level

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Application

2-氨基-5-溴吡啶用于研究 2-氨基-5-溴吡啶苯甲酸(1/1)共晶中的氢键模式 。其曾用于合成 2-氨基-5-溴代-吡啶酚-3-氨基-苯甲酸盐 和多环氮杂芳烃

General description

2-氨基-5-溴吡啶是一种溴化芳香胺试剂,用于通过还原胺化标记模型还原端寡糖

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Min Li et al.
Rapid communications in mass spectrometry : RCM, 17(13), 1462-1466 (2003-06-24)
Model reducing-end oligosaccharides were successfully labeled by a brominated aromatic amine reagent, 2-amino-5-bromopyridine (ABP), through reductive amination. Using either a combination of liquid chromatography/electrospray ionization mass spectrometry (LC/ESI-MS) with in-source fragmentation or liquid chromatography/electrospray ionization tandem mass spectrometry (LC/ESI-MS/MS), sequence
Tetrahedron Letters, 48, 5039-5039 (2007)
Madhukar Hemamalini et al.
Acta crystallographica. Section E, Structure reports online, 66(Pt 3), o664-o664 (2010-01-01)
In the title salt, C(5)H(6)BrN(2) (+)·C(7)H(6)NO(2) (-), the pyridine N atom of the 2-amino-5-bromo-pyridine mol-ecule is protonated. In the crystal, the protonated N atom and the 2-amino group are hydrogen-bonded to the carboxyl-ate O atoms via a pair of N-H⋯O
Madhukar Hemamalini et al.
Acta crystallographica. Section E, Structure reports online, 66(Pt 3), o663-o663 (2010-01-01)
In the title adduct, C(5)H(5)BrN(2)·C(7)H(6)O(2), the carboxyl group of the benzoic acid mol-ecule is twisted away from the attached ring by 12.97 (11)°. The 2-amino-5-bromo-pyridine mol-ecules inter-act with the carboxylic group of neighbouring benzoic acid mol-ecules through N-H⋯O and O-H⋯N hydrogen

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