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Merck
CN

123137

2-氨基苯硫酚

technical grade, 90%

别名:

2-巯基苯胺, 2-氨基苯硫醇, 邻氨基苯硫醇

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线性分子式:
H2NC6H4SH
化学文摘社编号:
分子量:
125.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-277-3
Beilstein/REAXYS Number:
606076
MDL number:
Assay:
90%
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InChI key

VRVRGVPWCUEOGV-UHFFFAOYSA-N

InChI

1S/C6H7NS/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

SMILES string

Nc1ccccc1S

grade

technical grade

assay

90%

Quality Level

bp

70-72 °C/0.2 mmHg (lit.)

mp

16-20 °C (lit.)

solubility

H2O: slightly soluble

density

1.17 g/mL at 25 °C (lit.)

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General description

2-Aminothiophenol couples with Amberlite XAD by means of an N=N spacer to prepare a new functionalized resin for on-line preconcentration of copper and cadmium.

Application

2-Aminothiophenol was used in one-pot synthesis of stable phosphonium ylides. It was also used in the synthesis of 2-[(2-benzothiazolylmethyl)thio]-benzenamine. It was used to functionalize silver nano particles for biological pH sensing based on surface enhanced Raman scattering.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

flash_point_f

174.2 °F

flash_point_c

79 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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分析证书(COA)

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One-pot synthesis of stable phosphonium ylides using 2-aminothiophenol.
Esmaili AA, et al.
Tetrahedron, 59(26), 4785-4788 (2003)
Dustin W Demoin et al.
Journal of chemical crystallography, 42(5), 508-512 (2012-06-02)
2-[2-benzothiazoylmethyl)thio]-benzenamine, which was first reported in 1898, was isolated from the reaction of bromoacetyl bromide and 2-aminothiophenol [1]. The product crystallized from an aqueous methanol solution of the reaction mixture to which nickel(II) acetate had been added. 2-[(2-benzothiazolylmethyl)thio]-benzenamine crystallized in
Valfredo Azevedo Lemos et al.
Talanta, 67(3), 564-570 (2008-10-31)
A new functionalized resin has been applied in an on-line preconcentration system for copper and cadmium determination. Amberlite XAD-2 was functionalized by coupling it to 2-aminothiophenol (AT-XAD) by means of an NN spacer. This resin was packed in a minicolumn
L S Jacobs et al.
Endocrinology, 115(3), 1210-1217 (1984-09-01)
Analogs of the aminothiol cysteamine (CySH) have been studied to clarify the structural features required for exertion of inhibitory effects on PRL. The inhibited functions examined were the detectability of PRL by RIA and the release of PRL from suspensions
Bob Muir et al.
Journal of chromatography. A, 1098(1-2), 156-165 (2005-11-30)
The reactivity of phosgene and perfluoroisobutylene (PFIB) towards 1,2-bis-nucleophiles was exploited to allow determination of these gases in air samples. 2-Aminothiophenol (ATP), 3,4-dimercaptotoluene (DMT) and 2-hydroxymethylpiperidine (HMP) were evaluated as bis-nucleophiles capable of forming thermally-stable derivatives with phosgene and PFIB

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