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Merck
CN

123137

2-氨基苯硫酚

technical grade, 90%

别名:

2-巯基苯胺, 2-氨基苯硫醇, 邻氨基苯硫醇

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线性分子式:
H2NC6H4SH
化学文摘社编号:
分子量:
125.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-277-3
Beilstein/REAXYS Number:
606076
MDL number:
Assay:
90%
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InChI key

VRVRGVPWCUEOGV-UHFFFAOYSA-N

InChI

1S/C6H7NS/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

SMILES string

Nc1ccccc1S

grade

technical grade

assay

90%

Quality Level

bp

70-72 °C/0.2 mmHg (lit.)

mp

16-20 °C (lit.)

solubility

H2O: slightly soluble

density

1.17 g/mL at 25 °C (lit.)

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General description

2-Aminothiophenol couples with Amberlite XAD by means of an N=N spacer to prepare a new functionalized resin for on-line preconcentration of copper and cadmium.

Application

2-Aminothiophenol was used in one-pot synthesis of stable phosphonium ylides. It was also used in the synthesis of 2-[(2-benzothiazolylmethyl)thio]-benzenamine. It was used to functionalize silver nano particles for biological pH sensing based on surface enhanced Raman scattering.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

flash_point_f

174.2 °F

flash_point_c

79 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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分析证书(COA)

Lot/Batch Number

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Dustin W Demoin et al.
Journal of chemical crystallography, 42(5), 508-512 (2012-06-02)
2-[2-benzothiazoylmethyl)thio]-benzenamine, which was first reported in 1898, was isolated from the reaction of bromoacetyl bromide and 2-aminothiophenol [1]. The product crystallized from an aqueous methanol solution of the reaction mixture to which nickel(II) acetate had been added. 2-[(2-benzothiazolylmethyl)thio]-benzenamine crystallized in
Valfredo Azevedo Lemos et al.
Talanta, 67(3), 564-570 (2008-10-31)
A new functionalized resin has been applied in an on-line preconcentration system for copper and cadmium determination. Amberlite XAD-2 was functionalized by coupling it to 2-aminothiophenol (AT-XAD) by means of an NN spacer. This resin was packed in a minicolumn
One-pot synthesis of stable phosphonium ylides using 2-aminothiophenol.
Esmaili AA, et al.
Tetrahedron, 59(26), 4785-4788 (2003)
Zhuyuan Wang et al.
Biosensors & bioelectronics, 23(6), 886-891 (2007-11-13)
We report pH sensing for biological applications based on surface enhanced Raman scattering (SERS) from silver nanoparticles functionalized with 2-aminothiophenol (2-aminobenzenethiol, 2-ABT). pH-dependent SERS spectra of the attached 2-ABT molecules enable one to sense the pH over the range of
Walid M I Hassan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 103, 378-387 (2012-12-26)
Novel Schiff base (H(2)L, 1,2-bis[(2-(2-mercaptophenylimino)methyl)phenoxy] ethane) derived from condensation of bisaldehyde and 2-aminothiophenol was prepared in a molar ratio 1:2. The ligand and its metal complexes are fully characterized with analytical and spectroscopic techniques. The metal complexes with Cr(III), Mn(II)

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