123358
1-氯-2-甲基-1-丙烯
98%
别名:
异丁烯氯
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关于此项目
线性分子式:
(CH3)2C=CHCl
化学文摘社编号:
分子量:
90.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-158-4
Beilstein/REAXYS Number:
1733843
MDL number:
Assay:
98%
InChI key
KWISWUFGPUHDRY-UHFFFAOYSA-N
InChI
1S/C4H7Cl/c1-4(2)3-5/h3H,1-2H3
SMILES string
C\C(C)=C\Cl
assay
98%
bp
68 °C (lit.)
density
0.92 g/mL at 25 °C (lit.)
functional group
alkyl halide, chloro
General description
1-氯-2-甲基丙烯经过硼氢化反应形成加合物，后者氧化后形成异丁醛。
Application
1-氯-2-甲基丙烯已用于研究α-氯烯烃的多红外光子激发。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
R E Cannon et al.
Molecular carcinogenesis, 29(4), 229-235 (2001-02-15)
This work was initiated to determine the potential for the Tg.AC mouse model to identify chemical carcinogens by an oral route of administration. Tg.AC v-Ha-ras transgenic mice were exposed to dimethyvinyl chloride (DMVC; 1-chloro-2-methylpropene), a structural analog of the human
Dimethylvinyl chloride.
Report on carcinogens : carcinogen profiles, 10, 109-110 (2004-08-25)
1-Chloro-2-methylpropene.
IARC monographs on the evaluation of carcinogenic risks to humans, 63, 315-324 (1995-01-01)
Formation of vinylidenecarbene intermediates in multiple infrared photon elimination reactions.
Reiser C and Steinfeld JI.
The Journal of Physical Chemistry, 84(6), 680-681 (1980)
P Srinivas et al.
Drug metabolism and disposition: the biological fate of chemicals, 16(3), 449-454 (1988-05-01)
Recent metabolism and disposition studies of 1-chloro-2-methylpropene (dimethylvinyl chloride) revealed cysteine and N-acetylcysteine conjugates of 3-chloro-2-methylpropenoic acid as the major metabolites. In the present studies we have investigated various steps in the metabolic pathway to determine which step was responsible
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