125512
环丙基苯基酮
97%
别名:
苯甲酰环丙烷
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关于此项目
线性分子式:
C6H5COC3H5
化学文摘社编号:
分子量:
146.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
222-458-2
Beilstein/REAXYS Number:
1860145
MDL number:
Assay:
97%
InChI key
PJRHFTYXYCVOSJ-UHFFFAOYSA-N
InChI
1S/C10H10O/c11-10(9-6-7-9)8-4-2-1-3-5-8/h1-5,9H,6-7H2
SMILES string
O=C(C1CC1)c2ccccc2
vapor density
5 (vs air)
assay
97%
Quality Level
bp
121-123 °C/15 mmHg (lit.)
mp
7-9 °C (lit.)
density
1.058 g/mL at 25 °C (lit.)
Application
Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Enolate formation from cyclopropyl ketones via iodide-induced ring opening and its use for stereoselective aldol reaction.
Han Z, et al.
Tetrahedron, 57(6), 987-995 (2001)
Cyclopropyl substituent effects on acid-catalyzed hydration of alkenes. Correlation by σ+ parameters.
Oyama K and Tidwell TT.
Journal of the American Chemical Society, 98(4), 947-951 (1976)
C Zimmermann et al.
Physical chemistry chemical physics : PCCP, 22(5), 2870-2877 (2020-01-09)
The two hydrogen bond solvation sites exhibited by the carbonyl group in acetophenone are influenced by alkylation of the methyl group in both the acetophenone and in the prototype solvent methanol, largely due to London dispersion forces. Phenyl docking and
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