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Merck
CN

128198

菊酸乙酯

95%

别名:

2,2-二甲基-3-(2-甲基-1-丙烯基)环丙烷-1-羧酸乙酯, 除虫菊一羧酸乙酯

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关于此项目

经验公式(希尔记法):
C12H20O2
化学文摘社编号:
分子量:
196.29
EC Number:
202-579-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
2045740
MDL number:
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assay

95%

refractive index

n20/D 1.461 (lit.)

bp

112 °C/10 mmHg (lit.)

density

0.906 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C1C(\C=C(\C)C)C1(C)C

InChI

1S/C12H20O2/c1-6-14-11(13)10-9(7-8(2)3)12(10,4)5/h7,9-10H,6H2,1-5H3

InChI key

VIMXTGUGWLAOFZ-UHFFFAOYSA-N

General description

Ethyl chrysanthemate is an allelochemical compound used as an attractant.

Application

Ethyl chrysanthemate was used in the preparation of trans-2,2-dimethylcyclopropyl nucleosides.


存储类别

10 - Combustible liquids

wgk

WGK 2

flash_point_f

183.2 °F - closed cup

flash_point_c

84 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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Min Chul Kook et al.
Archives of pharmacal research, 26(11), 887-891 (2003-12-10)
Novel trans-2,2-dimethylcyclopropyl nucleosides were synthesized as potential antiviral agents. The key intermediate, 3, was synthesized via five steps from ethyl chrysanthemate and condensed with purine bases using the Mitsunobu reaction to give six cyclopropyl nucleosides. These synthesized nucleosides did not
J P Morin et al.
Comptes rendus de l'Academie des sciences. Serie III, Sciences de la vie, 319(7), 595-602 (1996-07-01)
Ethyl 4-methyloctanoate, which has already been described in Oryctes monoceros, has been identified, using extracts of effluvia collected from males, as being a major component of the male pheromone of O. rhinoceros. Field trials have been carried out in North
K Mitsukura et al.
Journal of applied microbiology, 108(4), 1263-1270 (2009-09-26)
Alcaligenes sp. NBRC 14130 was found as a strain hydrolysing a mixture of (+/-)-trans- and (+/-)-cis ethyl chrysanthemates to (1R,3R)-(+)-trans-chrysanthemic acid. The Alcaligenes cells also have hydrolytic activity for 6-aminohexanoate-cyclic dimer (6-AHCD, 1,8-diazacyclotetradecane-2,9-dione). The correlation of function on the enzyme