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128554

1,5-己二烯

Name: 1,5-己二烯
Brand: ALDRICH

97%

别名:

Biallyl, Diallyl

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关于此项目

线性分子式:

H₂C=CHCH₂CH₂CH=CH₂

化学文摘社编号:

592-42-7

分子量:

82.14

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847866

EC Number:

209-754-7

Beilstein/REAXYS Number:

1731106

MDL number:

MFCD00008666

Assay:

97%

Form:

liquid

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属性

vapor pressure

367 mmHg ( 37.7 °C)

Quality Level

100

assay

97%

form

liquid

contains

Contains ~100ppm BHT as stabilizer

refractive index

n20/D 1.404 (lit.)

bp

60 °C (lit.)

mp

−141 °C (lit.)

density

0.692 g/mL at 25 °C (lit.)

functional group

allyl

storage temp.

2-8°C

SMILES string

C=CCCC=C

InChI

1S/C6H10/c1-3-5-6-4-2/h3-4H,1-2,5-6H2

InChI key

PYGSKMBEVAICCR-UHFFFAOYSA-N

说明

Application

1,5-己二烯可用于研究Pd（II）催化的官能化1,5-己二烯的环异构化。

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H319,H335

pcodes

P210 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-16.6 °F - closed cup

flash_point_c

-27 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Palladium(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes.

Björn Nelson et al.

Organic letters, 13(16), 4438-4441 (2011-07-29)

Scope and limitations of the Pd(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes have been studied. In situ NMR experiments indicate a challenging competition between various reaction pathways. A careful balance between substrate structure, nature of the precatalyst, and reaction conditions was required

Radical Cation/Radical Reactions: A Fourier Transform Ion Cyclotron Resonance Study of Allyl Radical Reacting with Aromatic Radical Cations.

Amber L Russell et al.

International journal of mass spectrometry, 287(1-3), 8-15 (2010-04-20)

A method for the study of reactions of open-shell neutrals (radicals) and radical cations is described. Pyrolysis (25-1500 degrees C) of thermally labile compounds, such as, 1,5-hexadiene via a Chen nozzle yields a seeded beam of reactive species in helium.

Remarkably Efficient Microwave-Assisted Cross-Metathesis of Lipids under Solvent-Free Conditions.

Aman Ullah et al.

ChemSusChem, 10(10), 2167-2174 (2017-03-02)

Catalytic transformation of renewable feedstocks into fine chemicals is in high demands and olefin metathesis is a sophisticated tool for biomass conversion. Nevertheless, the large-scale viability of such processes depends on the conversion efficiency, energy efficiency, catalytic activity, selective conversion

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全球贸易项目编号

货号	GTIN
128554-25G	04061837864810
128554-100G	04061838725714