128554
1,5-己二烯
97%
别名:
Biallyl, Diallyl
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关于此项目
线性分子式:
H2C=CHCH2CH2CH=CH2
化学文摘社编号:
分子量:
82.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-754-7
Beilstein/REAXYS Number:
1731106
MDL number:
产品名称
1,5-己二烯, 97%
InChI key
PYGSKMBEVAICCR-UHFFFAOYSA-N
InChI
1S/C6H10/c1-3-5-6-4-2/h3-4H,1-2,5-6H2
SMILES string
C=CCCC=C
vapor pressure
367 mmHg ( 37.7 °C)
assay
97%
form
liquid
contains
Contains ~100ppm BHT as stabilizer
refractive index
n20/D 1.404 (lit.)
bp
60 °C (lit.)
mp
−141 °C (lit.)
density
0.692 g/mL at 25 °C (lit.)
functional group
allyl
storage temp.
2-8°C
Quality Level
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Application
1,5-己二烯可用于研究Pd（II）催化的官能化1,5-己二烯的环异构化。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-16.6 °F - closed cup
flash_point_c
-27 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Amber L Russell et al.
International journal of mass spectrometry, 287(1-3), 8-15 (2010-04-20)
A method for the study of reactions of open-shell neutrals (radicals) and radical cations is described. Pyrolysis (25-1500 degrees C) of thermally labile compounds, such as, 1,5-hexadiene via a Chen nozzle yields a seeded beam of reactive species in helium.
Björn Nelson et al.
Organic letters, 13(16), 4438-4441 (2011-07-29)
Scope and limitations of the Pd(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes have been studied. In situ NMR experiments indicate a challenging competition between various reaction pathways. A careful balance between substrate structure, nature of the precatalyst, and reaction conditions was required
Richard G Closser et al.
ACS applied materials & interfaces, 11(24), 21988-21997 (2019-06-11)
The synthesis of an all-carbon backboned fluoropolymer using photoactivated molecular layer deposition (pMLD) is developed. pMLD is a vapor-phase, layer-by-layer, organic thin film synthesis method utilizing UV light, allowing for the creation of materials previously unavailable via thermal MLD. The
Aman Ullah et al.
ChemSusChem, 10(10), 2167-2174 (2017-03-02)
Catalytic transformation of renewable feedstocks into fine chemicals is in high demands and olefin metathesis is a sophisticated tool for biomass conversion. Nevertheless, the large-scale viability of such processes depends on the conversion efficiency, energy efficiency, catalytic activity, selective conversion
He Nan et al.
Journal of chromatography. A, 1523, 316-320 (2017-06-26)
Silver ion or argentation chromatography utilizes stationary phases containing silver ions for the separation of unsaturated compounds. In this study, a mixed-ligand silver-based ionic liquid (IL) was evaluated for the first time as a gas chromatographic (GC) stationary phase for
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