质量水平
方案
98%
表单
liquid
折射率
n20/D 1.4540 (lit.)
沸点
130-132 °C (lit.)
密度
0.828 g/mL at 25 °C (lit.)
SMILES字符串
C#CC1CCCCC1
InChI
1S/C8H12/c1-2-8-6-4-3-5-7-8/h1,8H,3-7H2
InChI key
SSDZYLQUYMOSAK-UHFFFAOYSA-N
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一般描述
环己基乙炔（乙炔基环己烷）与肝微粒体孵育时介导 NADPH 依赖性细胞色素 P-450 损失 。
应用
环己基乙炔（乙炔基环己烷）用于制备 [Os [(E)-CH = CHR] (= C = C = CPh2) (CH3CN) 2 (P (i) Pr3) 2] BF4 (R = Ph,Cy) 。
警示用语：
Danger
危险声明
危险分类
Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
64.4 °F - closed cup
闪点(°C)
18 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tamara Bolaño et al.
Journal of the American Chemical Society, 128(12), 3965-3973 (2006-03-23)
Treatment in acetonitrile at -30 C of the hydride-alkenylcarbyne complex [OsH([triple bond]CCH=CPh2)(CH3CN)2(P(i)Pr3)2][BF4]2 (1) with (t)BuOK produces the selective deprotonation of the alkenyl substituent of the carbyne and the formation of the bis-solvento hydride-allenylidene derivative [OsH(=C=C=CPh2)(CH3CN)2(P(i)Pr3)2]BF4 (2), which under carbon monoxide
Self-catalyzed inactivation of hepatic cytochrome P-450 by ethynyl substrates.
P R Ortiz de Montellano et al.
The Journal of biological chemistry, 255(12), 5578-5585 (1980-06-25)
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