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Merck
CN

129259

2,3-二甲基-2-丁烯

98%

别名:

四甲基乙烯

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关于此项目

线性分子式:
(CH3)2C=C(CH3)2
化学文摘社编号:
分子量:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-263-8
Beilstein/REAXYS Number:
1361357
MDL number:
Assay:
98%
Form:
liquid
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vapor pressure

215 mmHg ( 37.7 °C)

Quality Level

assay

98%

form

liquid

autoignition temp.

754 °F

refractive index

n20/D 1.412 (lit.)

bp

73 °C (lit.)

mp

−75 °C (lit.)

density

0.708 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C\C(C)=C(\C)C

InChI

1S/C6H12/c1-5(2)6(3)4/h1-4H3

InChI key

WGLLSSPDPJPLOR-UHFFFAOYSA-N

General description

2,3-Dimethyl-2-butene undergoes hydrolysis to form hydroxyl radical.

Application

2,3-Dimethyl-2-butene was used in the preparation of thexyl NHC-borane (diMe-Imd-BH2thexyl).


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pictograms

FlameHealth hazard

signalword

Danger

hcodes

Hazard Classifications

Asp. Tox. 1 - Flam. Liq. 2

存储类别

3 - Flammable liquids

flash_point_f

17.6 °F - closed cup

flash_point_c

-8 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xiangcheng Pan et al.
Journal of the American Chemical Society, 135(38), 14433-14437 (2013-08-29)
The hydroboration of alkenes of diverse structural types by assorted N-heterocyclic carbene boranes can be accomplished by addition of 5-10% diiodine. For example, reaction of 1,3-dimethylimidazol-2-ylidene borane (diMe-Imd-BH3) with 10% I2 followed by addition of 2,3-dimethyl-2-butene provided the corresponding thexyl
Maryline Pflieger et al.
Environmental science & technology, 47(12), 6239-6246 (2013-05-15)
In order to investigate the heterogeneous oxidation kinetics of the herbicide terbuthylazine (TERB), a stable and reproducible generation system of "dark" hydroxyl radical in the gas phase was developed and optimized using a PTR-MS. TERB was adsorbed on silica particles
P Di Mascio et al.
Free radical biology & medicine, 12(6), 471-478 (1992-01-01)
Ultraweak chemiluminescence arising from lipoperoxidation has been attributed by several authors to the radiative deactivation of singlet oxygen and triplet carbonyl products. The latter emitters have been suggested to come from annihilation of RO. and ROO. radicals as well as



全球贸易项目编号

货号GTIN
129259-100ML04061837864834
129259-1L04061837864841
129259-25ML04061838726148