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文件

安全信息

129593

Sigma-Aldrich

丙二酰胺

97%

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别名:
Malonodiamide
线性分子式:
CH2(CONH2)2
CAS号:
108-13-4
分子量:
102.09
Beilstein:
1751401
EC 号:
203-553-8
MDL编号:
MFCD00008034
PubChem化学物质编号:
24847915
NACRES:
NA.22

质量水平

100

检测方案

97%

形式

solid

mp

172-175 °C (lit.)

荧光

λex 367 nm; λem 445 nm (α-keto acid adduct)

SMILES字符串

NC(=O)CC(N)=O

InChI

1S/C3H6N2O2/c4-2(6)1-3(5)7/h1H2,(H2,4,6)(H2,5,7)

InChI key

WRIRWRKPLXCTFD-UHFFFAOYSA-N

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相关类别

一般描述

丙二酰胺衍生物是通过异氰酸酯、Meldrum′s酸、芳叉丙二腈和CH 2 Cl 2 中两个胺分子的一锅五组分缩合反应产生的。

应用

离子液体萃取剂用于从硝酸介质中萃取铕（iii）等三价稀土离子 。

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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P J Blackall et al.
Veterinary microbiology, 11(3), 301-306 (1986-03-01)
The effect of using two different techniques for the detection of substrate alkalinization by Bordetella avium and reference strains of Alcaligenes faecalis and B. bronchiseptica was evaluated. The techniques used were those described by Otto and Pickett and Hinz et
Zhong-Liu Wu et al.
The Journal of organic chemistry, 68(6), 2479-2482 (2003-03-15)
A variety of alpha,alpha-disubstituted malonamides undergo enantioselective hydrolysis with Rhodococcus sp. CGMCC 0497 to give challenging enantiopure alpha,alpha-disubstituted malonamic acids with up to >99% enantiomeric excesses and 98% chemical yields. The enantioselectivity originated from the effects of a highly enantioselective
S A Ansari et al.
Journal of hazardous materials, 161(2-3), 1323-1329 (2008-06-11)
A new chelating polymeric extraction chromatographic resin was prepared by chemical anchoring of N,N'-dimethyl-N,N'-dibutyl malonamide (DMDBMA) with chloromethylated Merrifield resin((R)). The grafted resin exhibited stronger binding for hexavalent and tetravalent actinides such as U(VI), Th(IV) and Pu(IV) over trivalent actinides
Oscar Saavedra et al.
Bioorganic & medicinal chemistry letters, 19(24), 6836-6839 (2009-11-10)
A family of thieno[3,2-b]pyridine based small molecule inhibitors of c-Met and VEGFR2 were designed based on lead structure 2. These compounds were shown to have IC(50) values in the low nanomolar range in vitro and were efficacious in human tumor
M J Barlow et al.
Solid state nuclear magnetic resonance, 1(4), 197-204 (1992-11-01)
Methyl tunnel frequencies, measured at 4 K, are found to be 455 +/- 8 kHz in methyl malonamide and 496 +/- 8 kHz in methyl ethyl ketone. The first is unaffected by deuteration of the amide groups. Measurements of the
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