方案
97%
表单
solid
mp
172-175 °C (lit.)
荧光
λex 367 nm; λem 445 nm (α-keto acid adduct)
SMILES字符串
NC(=O)CC(N)=O
InChI
1S/C3H6N2O2/c4-2(6)1-3(5)7/h1H2,(H2,4,6)(H2,5,7)
InChI key
WRIRWRKPLXCTFD-UHFFFAOYSA-N
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一般描述
丙二酰胺衍生物是通过异氰酸酯、Meldrum′s酸、芳叉丙二腈和CH 2 Cl 2 中两个胺分子的一锅五组分缩合反应产生的。
应用
离子液体萃取剂用于从硝酸介质中萃取铕(iii)等三价稀土离子 。
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Alok Rout et al.
Journal of hazardous materials, 221-222, 62-67 (2012-05-01)
The extraction behavior of U(VI), Pu(IV) and Am(III) from nitric acid medium by a solution of N,N-dimethyl-N,N-dioctyl-2-(2-hexyloxyethyl)malonamide (DMDOHEMA) in the room temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (C(4)mimNTf(2)), was studied. The distribution ratio of these actinides in DMDOHEMA/C(4)mimNTf(2) was measured as
Romain Diss et al.
Physical chemistry chemical physics : PCCP, 7(2), 264-272 (2005-01-21)
According to molecular dynamics simulations, uncomplexed malonamide ligands L and their neutral Eu(NO3)3L2 or charged EuL4(3+) complexes are surface active and adsorb at a water-"oil" interface, where "oil" is modeled by chloroform. Aqueous solvation at the interface is found to
Abbas Rahmati et al.
Molecular diversity, 17(3), 619-625 (2013-05-25)
A one-pot, five-component condensation reaction of isocyanide, Meldrum's acid, arylidene malononitrile, and two amine molecules in CH2Cl2 at ambient temperature to give malonamide derivatives is described.
L C Cerny et al.
Critical care medicine, 11(9), 739-743 (1983-09-01)
This study examines some of the biophysical properties of mixtures of whole blood with 3 different hydroxyethyl starch-hemoglobin (HES-Hgb) polymer blood substitutes. The polymers have about a 3-fold range of number average molecular weight and intrinsic viscosity range. The range
Jacqueline C Hargis et al.
Journal of the American Chemical Society, 130(51), 17471-17478 (2008-12-04)
A systematic study of various derivatives of malonaldehyde has been carried out to explore very short hydrogen bonds (r(OO) < 2.450 A). Various electron-withdrawing groups, including CN, NO(2), and BH(2), have been attached to the central carbon atom, C(2). To
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