129712
3-氨基巴豆酸甲酯
97%
别名:
3-氨基-2-丁烯酸甲酯
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线性分子式:
CH3C(NH2)=CHCOOCH3
化学文摘社编号:
分子量:
115.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
238-056-5
Beilstein/REAXYS Number:
956592
MDL number:
产品名称
3-氨基巴豆酸甲酯, 97%
InChI key
XKORCTIIRYKLLG-ONEGZZNKSA-N
InChI
1S/C5H9NO2/c1-4(6)3-5(7)8-2/h3H,6H2,1-2H3/b4-3+
SMILES string
COC(=O)\C=C(\C)N
assay
97%
form
solid
mp
81-83 °C (lit.)
functional group
amine
ester
Quality Level
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Application
3-氨基巴豆酸甲酯（3-氨基-2-丁烯酸甲酯）被用于合成具有潜在钙通道阻断活性的4-芳基-1,4-二氢吡啶。
General description
3-氨基古酸甲酯与结晶茚三酮发生无废物的固态级联反应 。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Gerd Kaupp et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(3), 594-600 (2002-02-22)
Crystalline ninhydrin (1) undergoes waste-free solid-state cascade reactions with dimedone, L-proline, three o-phenylenediamines, o-mercaptoaniline, two ureas, three thioureas, and methyl 3-aminocrotonate. The yields are quantitative and give pure crystalline products without workup just by milling stoichiometric mixtures of the crystalline
P Jain et al.
Die Pharmazie, 61(5), 400-405 (2006-05-27)
Synthesis of a new series of 4-aryl-1,4-dihydropyridines possessing potential calcium channel blocking activity along with good vasodilatory profile is reported. The compounds were synthesized using modified Hantzsch condensation of various aldehydes with methyl 3-aminocrotonate in the presence of a catalytic
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