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130036

N-甲基-4-哌啶酮

Name: <I>N</I>-甲基-4-哌啶酮
Brand: ALDRICH

97%

别名:

1-Methyl-4-piperidinone

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关于此项目

经验公式（希尔记法）:

C₆H₁₁NO

化学文摘社编号:

1445-73-4

分子量:

113.16

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847937

EC Number:

215-895-5

Beilstein/REAXYS Number:

106924

MDL number:

MFCD00006191

Assay:

97%

Form:

liquid

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属性

reg. compliance

suitable for FDA C-010.02

Quality Level

100

assay

97%

form

liquid

density

0.92 g/mL at 25 °C (lit.)

application(s)

PFAS testing

functional group

ketone

storage temp.

2-8°C

SMILES string

CN1CCC(=O)CC1

InChI

1S/C6H11NO/c1-7-4-2-6(8)3-5-7/h2-5H2,1H3

InChI key

HUUPVABNAQUEJW-UHFFFAOYSA-N

说明

Application

N-甲基-4-哌啶酮可作为反应物，用于制备：

螺环哌啶环，通过与丙二腈与亲电试剂或Michael受体反应。
(3E,5E)-1-甲基-3,5-双(苯亚甲基)-4-哌啶酮，通过Michael加成反应与苯甲醛反应，然后发生O-环化/消除连续反应。
N,N′-Dimethylbispidinone，使用双曼尼希冷凝法。

pictograms

GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

136.4 °F - closed cup

flash_point_c

58 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Analogs of sparteine. I. Reexamination of the reaction of N-methyl-4-piperidone with formaldehyde and methylamine. Revised synthesis of N, N'-dimethylbispidinone

Smissman EE, et al.

The Journal of Organic Chemistry, 40, 251-252 (1975)

Dissymmetric pyridyl-substituted 3,5-bis(arylidene)-4-piperidones as anti-hepatoma agents by inhibiting NF-κB pathway activation.

Bin-Rong Yao et al.

European journal of medicinal chemistry, 167, 187-199 (2019-02-17)

To get new anti-hepatoma agents with anti-inflammatory activity and hypotoxicity, a series of dissymmetric pyridyl-substituted 3,5-bis(arylidene)-4-piperidones (BAPs, 25-82) were designed and synthesized. Many of them exhibited potential anti-hepatoma properties against human hepatocellular carcinoma cell lines (HepG2, QGY-7703, SMMC-7721) and hypotoxicity

Novel route to spiropiperidines using N-methyl-4-piperidone, malononitrile and electrophiles

Lakshmi NV, et al.

Tetrahedron Letters, 53, 1282-1286 (2012)

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全球贸易项目编号

货号	GTIN
130036-100ML	04061838726698
130036-5ML	04061838726704
130036-500ML	04061838134745