130176
4-硝基苯甲醛
98% (GC)
别名:
p-Nitrobenzaldehyde
质量水平
方案
98% (GC)
mp
103-106 °C (lit.)
官能团
aldehyde
nitro
SMILES字符串
[O-][N+](=O)c1ccc(C=O)cc1
InChI
1S/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H
InChI key
BXRFQSNOROATLV-UHFFFAOYSA-N
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应用
4-硝基苯甲醛可用于制备高烯丙基醇。它还可用于开发和评估一系列三肽有机催化剂。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Sens. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Niels J M Pijnenburg et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(15), 4858-4868 (2013-02-26)
This paper describes a mechanistic study of the SCS-pincer Pd(II)-catalyzed auto-tandem reaction consisting of the stannylation of cinnamyl chloride with hexamethylditin, followed by an electrophilic allylic substitution of the primary tandem-reaction product with 4-nitrobenzaldehyde to yield homoallylic alcohols as the
Saadi Bayat et al.
Chirality, 25(11), 726-734 (2013-08-24)
A series of tripeptide organocatalysts containing a secondary amine group and two amino acids with polar side chain units were developed and evaluated in the direct asymmetric intermolecular aldol reaction of 4-nitrobenzaldehyde and cyclohexanone. The effectiveness of short polar peptides
H Maheswaran et al.
Chemical communications (Cambridge, England), (39)(39), 4066-4068 (2006-10-07)
The dichloro[(-)-sparteine-N,N']copper(II) complex provides Henry adducts with high enantioselectivities (73-97% ee) in Henry reaction between nitromethane and various aldehydes.
Chao Li et al.
Journal of biotechnology, 150(4), 539-545 (2010-10-21)
Several proteases, especially pepsin, were observed to directly catalyze asymmetric aldol reactions. Pepsin, which displays well-documented proteolytic activity under acidic conditions, exhibited distinct catalytic activity in a crossed aldol reaction between acetone and 4-nitrobenzaldehyde with high yield and moderate enantioselectivity.
Jinmo Kim et al.
Analytical chemistry, 77(13), 4137-4141 (2005-07-01)
A chemical derivatization technique in time-of-flight secondary ion mass spectrometry (TOF-SIMS) has been developed to quantify the surface density of amine groups of plasma-polymerized ethylenediamine thin film deposited on a glass surface by inductively coupled plasma chemical vapor deposition. Chemical
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