130176
4-硝基苯甲醛
98% (GC)
别名:
p-Nitrobenzaldehyde
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关于此项目
线性分子式:
O2NC6H4CHO
化学文摘社编号:
分子量:
151.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-084-5
Beilstein/REAXYS Number:
386796
MDL number:
产品名称
4-硝基苯甲醛, 98% (GC)
InChI key
BXRFQSNOROATLV-UHFFFAOYSA-N
InChI
1S/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H
SMILES string
[O-][N+](=O)c1ccc(C=O)cc1
assay
98% (GC)
mp
103-106 °C (lit.)
functional group
aldehyde
nitro
Quality Level
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Application
4-硝基苯甲醛可用于制备高烯丙基醇。它还可用于开发和评估一系列三肽有机催化剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Saadi Bayat et al.
Chirality, 25(11), 726-734 (2013-08-24)
A series of tripeptide organocatalysts containing a secondary amine group and two amino acids with polar side chain units were developed and evaluated in the direct asymmetric intermolecular aldol reaction of 4-nitrobenzaldehyde and cyclohexanone. The effectiveness of short polar peptides
Niels J M Pijnenburg et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(15), 4858-4868 (2013-02-26)
This paper describes a mechanistic study of the SCS-pincer Pd(II)-catalyzed auto-tandem reaction consisting of the stannylation of cinnamyl chloride with hexamethylditin, followed by an electrophilic allylic substitution of the primary tandem-reaction product with 4-nitrobenzaldehyde to yield homoallylic alcohols as the
H Maheswaran et al.
Chemical communications (Cambridge, England), (39)(39), 4066-4068 (2006-10-07)
The dichloro[(-)-sparteine-N,N']copper(II) complex provides Henry adducts with high enantioselectivities (73-97% ee) in Henry reaction between nitromethane and various aldehydes.
Anant Prakash et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(3-4), 356-362 (2010-04-27)
The new Schiff bases N,N'-bis (4-nitro benzaldehyde) ethylenediamine (L(1)) and N,N'-bis (acetophenone) ethylenediamine (L(2)) and its Zn(II), Cd(II) complexes were synthesized and characterized by different physicochemical studies. Vibrational spectra indicate coordination of metal ion through azomethine nitrogen and acetate/nitrate ions.
Chao Li et al.
Journal of biotechnology, 150(4), 539-545 (2010-10-21)
Several proteases, especially pepsin, were observed to directly catalyze asymmetric aldol reactions. Pepsin, which displays well-documented proteolytic activity under acidic conditions, exhibited distinct catalytic activity in a crossed aldol reaction between acetone and 4-nitrobenzaldehyde with high yield and moderate enantioselectivity.
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