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130621

戊二腈

Name: 戊二腈
Brand: ALDRICH

99%

别名:

1,3-二氰基丙烷

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关于此项目

线性分子式:

NC(CH₂)₃CN

化学文摘社编号:

544-13-8

分子量:

94.11

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847973

EC Number:

208-861-6

Beilstein/REAXYS Number:

1738385

MDL number:

MFCD00001970

Assay:

99%

Form:

liquid

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属性

Quality Level

200

assay

99%

form

liquid

refractive index

n20/D 1.434 (lit.)

bp

285-287 °C (lit.)

mp

−29 °C (lit.)

solubility

H₂O: soluble, alcohol: soluble, chloroform: soluble

density

0.995 g/mL at 25 °C (lit.)

functional group

nitrile

SMILES string

N#CCCCC#N

InChI

1S/C5H6N2/c6-4-2-1-3-5-7/h1-3H2

InChI key

ZTOMUSMDRMJOTH-UHFFFAOYSA-N

说明

Application

Glutaronitrile can be used as:

An electrolyte additive in high energy/power Li-ion batteries.
A glutarate ligand source to prepare zinc glutarate (ZnGA) by reacting with zinc perchlorate hexahydrate.
A reactant to synthesize pentanedithioamide by reacting with Lawesson′s reagent in the presence of boron trifluoride etherate (BF₃.OEt₂).

Glutaronitrile (1,3-Dicyanopropane) was used in the preparation of dicarbonyl compounds.

pictograms

GHS06

signalword

Danger

hcodes

H301

pcodes

P264 - P270 - P301 + P310 - P405 - P501

Hazard Classifications

Acute Tox. 3 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

233.6 °F - closed cup

flash_point_c

112 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles: synthesis of alkyl aryl ketones, diketone compounds, and 2-arylbenzo[b]furans.

Xingyong Wang et al.

The Journal of organic chemistry, 78(11), 5273-5281 (2013-05-15)

A palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles has been developed, leading to a wide range of alkyl aryl ketones with moderate to excellent yields. Moreover, several dinitriles (e.g., malononitrile, glutaronitrile, and adiponitrile) were applicable to this process for

γ-butyrolactone and glutaronitrile as 5 V electrolyte additive and its electrochemical performance for LiNi0. 5Mn1. 5O4

Xu Yun, et al.

Journal of alloys and compounds, 698, 207-214 (2017)

Rotational spectroscopy and astronomical search for glutaronitrile★.

C Cabezas et al.

Astronomy and astrophysics, 636 (2020-05-28)

Nitriles constitute almost 15% of the molecules observed in the interstellar medium (ISM), surprisingly only two dinitriles have been detected in the ISM so far. The lack of astronomical detections for dinitriles may be partly explained by the absence of

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全球贸易项目编号

货号	GTIN
130621-25ML	04061838345769
130621-100ML	04061838345752