Merck
CN
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文件

安全信息

130621

Sigma-Aldrich

戊二腈

99%

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别名:
1,3-二氰基丙烷
线性分子式:
NC(CH2)3CN
CAS号:
544-13-8
分子量:
94.11
Beilstein:
1738385
EC 号:
208-861-6
MDL编号:
MFCD00001970
PubChem化学物质编号:
24847973
NACRES:
NA.22

检测方案

99%

形式

liquid

折射率

n20/D 1.434 (lit.)

bp

285-287 °C (lit.)

mp

−29 °C (lit.)

溶解性

H2O: soluble
alcohol: soluble
chloroform: soluble

密度

0.995 g/mL at 25 °C (lit.)

SMILES string

N#CCCCC#N

InChI

1S/C5H6N2/c6-4-2-1-3-5-7/h1-3H2

InChI key

ZTOMUSMDRMJOTH-UHFFFAOYSA-N

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相关类别

应用

Glutaronitrile (1,3-Dicyanopropane) was used in the preparation of dicarbonyl compounds.
Glutaronitrile can be used as:
  • An electrolyte additive in high energy/power Li-ion batteries.
  • A glutarate ligand source to prepare zinc glutarate (ZnGA) by reacting with zinc perchlorate hexahydrate.
  • A reactant to synthesize pentanedithioamide by reacting with Lawesson′s reagent in the presence of boron trifluoride etherate (BF3.OEt2).

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H301

危险分类

Acute Tox. 3 Oral

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

233.6 °F

闪点(°C)

112 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Hydrothermal synthesis of single-crystalline zinc glutarate and its structural determination
Kim Jong-Seong, et al.
Chemistry of Materials, 16(16), 2981-2983 (2004)
The BF3.OEt2-Assisted Conversion of Nitriles into Thioamides with Lawesson?s Reagent
Nagl Michael, et al.
Synthesis, 2008(24), 4012-4018 (2008)
C Cabezas et al.
Astronomy and astrophysics, 636 (2020-05-28)
Nitriles constitute almost 15% of the molecules observed in the interstellar medium (ISM), surprisingly only two dinitriles have been detected in the ISM so far. The lack of astronomical detections for dinitriles may be partly explained by the absence of
γ-butyrolactone and glutaronitrile as 5 V electrolyte additive and its electrochemical performance for LiNi0. 5Mn1. 5O4
Xu Yun, et al.
Journal of alloys and compounds, 698, 207-214 (2017)
Xingyong Wang et al.
The Journal of organic chemistry, 78(11), 5273-5281 (2013-05-15)
A palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles has been developed, leading to a wide range of alkyl aryl ketones with moderate to excellent yields. Moreover, several dinitriles (e.g., malononitrile, glutaronitrile, and adiponitrile) were applicable to this process for
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