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130621

戊二腈

Name: 戊二腈
Brand: ALDRICH

99%

别名:

1,3-二氰基丙烷

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关于此项目

线性分子式:

NC(CH₂)₃CN

化学文摘社编号:

544-13-8

分子量:

94.11

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24847973

EC Number:

208-861-6

Beilstein/REAXYS Number:

1738385

MDL number:

MFCD00001970

Assay:

99%

Form:

liquid

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属性

Quality Level

200

assay

99%

form

liquid

refractive index

n20/D 1.434 (lit.)

bp

285-287 °C (lit.)

mp

−29 °C (lit.)

solubility

H₂O: soluble, alcohol: soluble, chloroform: soluble

density

0.995 g/mL at 25 °C (lit.)

functional group

nitrile

SMILES string

N#CCCCC#N

InChI

1S/C5H6N2/c6-4-2-1-3-5-7/h1-3H2

InChI key

ZTOMUSMDRMJOTH-UHFFFAOYSA-N

说明

Application

Glutaronitrile can be used as:

An electrolyte additive in high energy/power Li-ion batteries.
A glutarate ligand source to prepare zinc glutarate (ZnGA) by reacting with zinc perchlorate hexahydrate.
A reactant to synthesize pentanedithioamide by reacting with Lawesson′s reagent in the presence of boron trifluoride etherate (BF₃.OEt₂).

Glutaronitrile (1,3-Dicyanopropane) was used in the preparation of dicarbonyl compounds.

pictograms

GHS06

signalword

Danger

hcodes

H301

pcodes

P264 - P270 - P301 + P310 - P405 - P501

Hazard Classifications

Acute Tox. 3 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

233.6 °F - closed cup

flash_point_c

112 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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γ-butyrolactone and glutaronitrile as 5 V electrolyte additive and its electrochemical performance for LiNi0. 5Mn1. 5O4

Xu Yun, et al.

Journal of alloys and compounds, 698, 207-214 (2017)

Palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles: synthesis of alkyl aryl ketones, diketone compounds, and 2-arylbenzo[b]furans.

Xingyong Wang et al.

The Journal of organic chemistry, 78(11), 5273-5281 (2013-05-15)

A palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles has been developed, leading to a wide range of alkyl aryl ketones with moderate to excellent yields. Moreover, several dinitriles (e.g., malononitrile, glutaronitrile, and adiponitrile) were applicable to this process for

Hydrothermal synthesis of single-crystalline zinc glutarate and its structural determination

Kim Jong-Seong, et al.

Chemistry of Materials, 16(16), 2981-2983 (2004)

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全球贸易项目编号

货号	GTIN
130621-100ML	04061838345752
130621-25ML	04061838345769