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Merck
CN

13112

powder, ≥99%

别名:

镁元素

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关于此项目

经验公式(希尔记法):
Mg
化学文摘社编号:
分子量:
24.31
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
38110201
UNSPSC Code:
12141502
EC Number:
231-104-6
MDL number:
Beilstein/REAXYS Number:
4948473
Assay:
≥99%
Form:
powder
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Quality Level

InChI key

FYYHWMGAXLPEAU-UHFFFAOYSA-N

InChI

1S/Mg

SMILES string

[Mg]

vapor pressure

1 mmHg ( 621 °C)

assay

≥99%

form

powder

autoignition temp.

950 °F

reaction suitability

reagent type: reductant

resistivity

4.46 μΩ-cm, 20°C

impurities

≤0.05% insoluble in HCl

bp

1090 °C (lit.)

mp

648 °C (lit.)

density

1.74 g/mL at 25 °C (lit.)

cation traces

Fe: ≤500 mg/kg

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Application

镁(粉)可用作还原剂以合成:
  • 钛合金氢化物粉末,通过氢气气氛下还原升级钛渣(UGS)。      
  • 通过球磨法从赤铁矿(α-Fe2O3)制备超细金属铁(bcc-Fe)粉。

还可用作还原剂,用于钌(III)络合物催化原子转移自由基加成(ATRA)和环化(ATRC)反应。镁不能产生自由基,但能生成和再生具有催化活性的钌(II)。

Analysis Note

外观:银灰色

pictograms

Flame

signalword

Danger

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Flam. Sol. 1 - Self-heat. 1 - Water-react. 2

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ultrafine spinel powders by flame spray pyrolysis of a magnesium aluminum double alkoxide.
Bickmore CR, et al.
Journal of the American Chemical Society, 79(5), 1419-1423 (1996)
Katrin Thommes et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(24), 6899-6907 (2007-06-05)
A new catalytic procedure for atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl(2)Cp*(PPh3)] (Cp*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild conditions with high efficiency. In most
Hyperbranched polyalkenylsilanes by hydrosilylation with platinum catalysts. I. Polymerization
Drohmann C, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(4), 741-751 (2000)
Uttley C.
Magnesium, 4-4 null
Shuvendu Biswas et al.
Nature chemistry, 5(7), 613-620 (2013-06-22)
The development of nanocarriers that selectively release guest molecules on sensing a particular biological signal is being actively pursued in nanomedicine for diagnostic and therapeutic purposes. Here we report a protein-based nanocarrier that opens in the presence of intracellular adenosine-5'-triphosphate

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