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Merck
CN

131377

1,10-菲啰啉

≥99%

别名:

o-phenanthroline

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关于此项目

经验公式（希尔记法）:
C12H8N2
化学文摘社编号:
66-71-7
分子量:
180.21
PubChem Substance ID:
24848008
eCl@ss:
39210124
UNSPSC Code:
12352100
NACRES:
NA.22
EC Number:
200-629-2
MDL number:
MFCD00011678

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产品名称

1,10-菲啰啉, ≥99%

InChI key

DGEZNRSVGBDHLK-UHFFFAOYSA-N

InChI

1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H

SMILES string

c1cnc2c(c1)ccc3cccnc23

assay

≥99%

form

powder

mp

114-117 °C (lit.)

Quality Level

200

Gene Information

human ... FNTA(2339)

相关类别

Application

1,10-菲咯啉可用作：
  • 阴极缓冲层，以提高有机太阳能电池的效率。
  • 常规螯合剂，用于研究其在Fenton反应-鲁米诺化学发光系统中的功效。
  • 温和的铜(II)催化有机硼酸和亚磺酸盐的交叉偶联的配体，从而形成芳基和烯基砜。
  • 一种用于金属分光光测定和二氧化碳光催化还原的通用配体。
  • 金属大环化合物合成砌块。

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

hcodes

H301,H410

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB6364
MKCV9740
SDBB1067
MKCV3595
STBL1289

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What is the difference between 1,10-Phenanthroline Products 131377 and 320056?

    Product 320056 is the monohydrate form and 131377 has no specification on water content. Both can make a copper complex, since they are the same ligand.

  6. Can Product 131377, 1,10-Phenanthroline, be used for cell culture?

    Sigma-Aldrich does not have any references for the use of 1,10-phenanthroline in cell culture.

  7. What is the solubility of Product 131377, 1,10-Phenanthroline?

    1,10-Phenanthroline is soluble in methanol at 500 micrograms per mL, or in water at 3 milligrams per mL. It is also soluble in benzene and acetone.

  8. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Mitsuhiro Wada et al.
Luminescence : the journal of biological and chemical luminescence, 29(7), 955-958 (2014-01-10)
In vitro screening of a Fe(2+) -chelating effect using a Fenton's reaction-luminol chemiluminescence (CL) system is described. The luminescence between the reactive oxygen species generated by the Fenton's reaction and luminol was decreased on capturing Fe(2+) using a chelator. The
Neville S Ng et al.
Dalton transactions (Cambridge, England : 2003), 42(9), 3196-3209 (2012-12-13)
Copper(II) (1(Cu)-21(Cu)) and previously established experimental anticancer platinum(II) metallointercalator complexes (1(Pt)-16(Pt)) have been prepared and investigated for their antimicrobial properties. These complexes are of the general structure [M(I(L))(A(L))](2+) where I(L) represents functionalised 1,10-phenanthrolines (1(IL)-10(IL)), and A(L) represents 1,2-diaminoethane, 1S,2S- or
Catalysis by Metal Complexes, 14, 217-217 (1993)
Luiza Notini et al.
Environmental science & technology, 53(15), 8883-8891 (2019-07-10)
Surface defects have been shown to facilitate electron transfer between Fe(II) and goethite (α-FeOOH) in abiotic systems. It is unclear, however, whether defects also facilitate microbial goethite reduction in anoxic environments where electron transfer between cells and Fe(III) minerals is
Chunming Sun et al.
ACS applied materials & interfaces, 6(2), 739-744 (2014-01-07)
We reported a significant improvement in the efficiency of organic solar cells by introducing hybrid TiO2:1,10-phenanthroline as a cathode buffer layer. The devices based on polymer thieno[3,4-b]thiophene/benzodithiophene:[6,6]-phenyl C71-butyric acid methyl ester (PTB7:PC71BM) with hybrid buffer layer exhibited an average power
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