132039
1,2,4-三乙酰氧基苯
97%
别名:
1,2,4-苯三酚醋酸酯
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关于此项目
线性分子式:
(CH3CO2)3C6H3
化学文摘社编号:
分子量:
252.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
210-327-2
MDL number:
Assay:
97%
Form:
solid
InChI key
AESFGSJWSUZRGW-UHFFFAOYSA-N
InChI
1S/C12H12O6/c1-7(13)16-10-4-5-11(17-8(2)14)12(6-10)18-9(3)15/h4-6H,1-3H3
SMILES string
CC(=O)Oc1ccc(OC(C)=O)c(OC(C)=O)c1
assay
97%
form
solid
mp
98-100 °C (lit.)
functional group
ester
Quality Level
Application
1,2,4-Triacetoxybenzene can be used as a starting material:
- To prepare aminated hydroxynaphthazarins, echinamines A and B.
- To synthesize 6,7-dihydroxychromenones, which are further used to prepare various crown ethers.
- In the total synthesis of natural product santalin Y.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Nataly D Pokhilo et al.
Journal of natural products, 69(8), 1125-1129 (2006-08-29)
The first total synthesis of two marine aminated hydroxynaphthazarins, echinamines A (3-amino-7-ethyl-2,5,6,8-tetrahydroxy-1,4-naphthoquinone) and B (2-amino-7-ethyl-3,5,6,8-tetrahydroxy-1,4-naphthoquinone), produced by the sea urchin Scaphechinus mirabilis is described. This was achieved from 1,2,4-triacetoxybenzene (13) through a sequence involving double Fries rearrangement of 13, reduction
Biomimetic total synthesis of santalin Y
Strych S, et al.
Angewandte Chemie (International Edition in English), 54, 5079-5083 (2015)
Synthesis of Echinamines A and B, the First Aminated Hydroxynaphthazarins Produced by the Sea Urchin Scaphechinus m irabilis and Its Analogues
Pokhilo ND, et al.
Journal of Natural Products, 69, 1125-1129 (2006)
The synthesis of novel crown ethers, part ix, 3-phenyl chromenone-crown ethers
Bulut M and Erk CL
Journal of Heterocyclic Chemistry, 38, 1291-1295 (2001)
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