132551
1,2-二氨基环己烷（顺反异构体混合物）
99%
别名:
1,2-环己二胺, 99% 葡萄糖溶液
蒸汽压
0.4 mmHg ( 20 °C)
质量水平
方案
99%
表单
liquid
折射率
n20/D 1.49 (lit.)
沸点
92-93 °C/18 mmHg (lit.)
密度
0.931 g/mL at 25 °C (lit.)
SMILES字符串
NC1CCCCC1N
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2
InChI key
SSJXIUAHEKJCMH-UHFFFAOYSA-N
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一般描述
1,2-二氨基环己烷与同手性化合物以及外消旋形式的 反式 -1,2-二氨基环己烷与对苯二甲醛发生非模板反应，生成 (3 + 3)-环缩合分子三角形 。它作为配体与有机锡形成络合物，作为金属类抗肿瘤药物具有潜在的应用价值 。
应用
将 1，2-二氨基环己烷用于手性钌 (Ⅳ) 氧配合物的合成 。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
(3+ 3)-Cyclocondensation of the enantiopure and racemic forms of trans-1, 2-diaminocyclohexane with terephthaldehyde. Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns.
Chadim M, et al.
Tetrahedron Asymmetry, 12(1), 127-133 (2001)
Chiral ruthenium (IV)-oxo complexes. Structure, reactivities of [Ru (terpy)(Nn N) O]2+Nn N= N, N, N', N'-tetramethyl-1, 2-diaminocyclohexane) and [Ru (Me3 tacn)(cbpy) O]2+ (cbpy=(-)-3, 3'-[(4 S-trans)-1, 3-dioxolane-4, 5-dimethyl]-2, 2'-bipyridine).
Cheng WC, et al.
Inorgorganica Chimica Acta, 242(1), 105-113 (1996)
J J Bonire et al.
Journal of inorganic biochemistry, 83(2-3), 217-221 (2001-03-10)
Platinum compounds containing the ligand 1,2-diaminocyclohexane (DACH) such as tetraplatin [PtCl4(DACH)] have been found to be active in cisplatin-resistant tumour models. In an attempt to develop novel metal-based drugs with a different therapeutic profile to cisplatin, we have synthesised a
Robert Häner et al.
Journal of the American Chemical Society, 132(21), 7466-7471 (2010-05-13)
Oligopyrenotides, abiotic oligomers that exhibit significant structural analogies to the nucleic acids, are described. They are composed of achiral, phosphodiester-linked pyrene building blocks and a single chiral 1,2-diaminocyclohexane unit. These oligomers form stable hybrids in aqueous solution. Hybridization is based
Farukh Arjmand et al.
Chirality, 23(3), 250-259 (2010-10-12)
A new chiral series of potential antitumor metal-based complexes 1-3(a and b) of L- and D-tryptophan have been synthesized and thoroughly characterized. Both enantiomers of 1-3 bind DNA noncovalently via phosphate interaction with slight preference of metal center for covalent
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