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Merck
CN

132985

巴豆醛,主要为反式

90%

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线性分子式:
CH3CH=CHCHO
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
MDL number:
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vapor density

2.41 (vs air)

vapor pressure

32 mmHg ( 20 °C)

assay

90%

autoignition temp.

320 °F

expl. lim.

19.5 %

impurities

8-10% water

refractive index

n20/D 1.4362 (lit.)

bp

104 °C (lit.)

mp

−76 °C (lit.)

solubility

water: soluble 18.1g/100g at 20 °C, water: soluble 19.2g/100g at 5 °C

density

0.846 g/mL at 25 °C (lit.)

SMILES string

[H]\C(C)=C(\[H])C([H])=O

InChI

1S/C4H6O/c1-2-3-4-5/h2-4H,1H3/b3-2+

InChI key

MLUCVPSAIODCQM-NSCUHMNNSA-N

General description

Crotonaldehyde on hydrogenation over Pt/SiO2 and Pt/TiO2 catalysts yields butyraldehyde and crotylalcohol depending on the size of the Pt particles and the promotion by surface oxides. It forms adducts with oligodeoxynucleotides containing 1,N2-deoxyguanosine residues and forms crosslinks with the tetrapeptide Lys-Trp-Lys-Lys.

Application

Crotonaldehyde was used to study the kinetics of the reaction of acrolein,crotonaldehyde and pivalaldehyde with Cl atoms.




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