133051
2-甲基-1-丁醇
≥99%
别名:
(±)-2-Methyl-1-butanol, Active amyl alcohol, sec-Butylcarbinol
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关于此项目
线性分子式:
C2H5CH(CH3)CH2OH
化学文摘社编号:
分子量:
88.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
205-289-9
MDL number:
Assay:
≥99%
Form:
liquid
InChI key
QPRQEDXDYOZYLA-UHFFFAOYSA-N
InChI
1S/C5H12O/c1-3-5(2)4-6/h5-6H,3-4H2,1-2H3
SMILES string
CCC(C)CO
vapor density
3 (vs air)
vapor pressure
3 mmHg ( 20 °C)
assay
≥99%
form
liquid
autoignition temp.
725 °F
expl. lim.
10 %
refractive index
n20/D 1.410±0.002 (lit.)
bp
130 °C mmHg (lit.)
solubility
water: slightly soluble 3.6g/a00g at 30 °C, alcohol: miscible, diethyl ether: miscible
density
0.819 g/mL at 20 °C (lit.), 0.815 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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General description
S -(-)-2-甲基-1-丁醇是合成手性液晶的前体 。它是一种潜在的新型生物燃料 。
Application
2-甲基-1-丁醇被用于 1，2-苯并二烯亚砜的光解氧研究 。
signalword
Danger
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
108.5 °F - closed cup
flash_point_c
42.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
法规信息
危险化学品
此项目有
A Comprehensive Approach to (S)-(-)-2-Methyl-1-Butanol as a Convenient Precursor for Synthesis of Chiral Liquid Crystals.
Kaszynski P and Jawdosiuk M.
Mol. Cryst. Liq. Cryst., 174(1), 21-37 (1989)
Anthony F Cann et al.
Applied microbiology and biotechnology, 81(1), 89-98 (2008-09-02)
Recent progress has been made in the production of higher alcohols by harnessing the power of natural amino acid biosynthetic pathways. Here, we describe the first strain of Escherichia coli developed to produce the higher alcohol and potential new biofuel
Erik R Abels et al.
Cell reports, 28(12), 3105-3119 (2019-09-19)
Gliomas are primary, diffusely infiltrating brain tumors. Microglia are innate immune cells in the CNS and make up a substantial portion of the tumor mass. Glioma cells shape their microenvironment, communicating with and reprogramming surrounding cells, resulting in enhanced angiogenesis
E Lucien et al.
The Journal of organic chemistry, 66(13), 4576-4579 (2001-06-26)
We report that the photodeoxygenation of 1,2-benzodiphenylene sulfoxide, 1, generates an intermediate capable of oxidizing the solvent benzene to phenol. The reactivity of the intermediate was probed with various substrates (2-methylbutane, chloride ion, and para-substituted aryl sulfides). The intermediate produced
Marianthi Karali et al.
PloS one, 6(7), e22166-e22166 (2011-08-06)
Gene transfer using adeno-associated viral (AAV) vectors has been successfully applied in the retina for the treatment of inherited retinal dystrophies. Recently, microRNAs have been exploited to fine-tune transgene expression improving therapeutic outcomes. Here we evaluated the ability of retinal-expressed
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