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Merck
CN

133280

异腈基正丁烷

97%

别名:

1-叔丁基异腈, 1-异氰基丁烷, 丁基异腈, 正丁基异腈

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关于此项目

线性分子式:
CH3(CH2)3NC
化学文摘社编号:
分子量:
83.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-458-7
MDL number:
Assay:
97%
Form:
liquid
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Quality Level

assay

97%

form

liquid

refractive index

n20/D 1.396 (lit.)

density

0.795 g/mL at 25 °C (lit.)

functional group

amine, isonitrile

storage temp.

2-8°C

SMILES string

CCCC[N+]#[C-]

InChI

1S/C5H9N/c1-3-4-5-6-2/h3-5H2,1H3

InChI key

FSBLVBBRXSCOKU-UHFFFAOYSA-N

Application

用异氰酸丁酯研究了从 生氢一氧化碳嗜热菌中分离得到的一氧化碳脱氢酶-II的晶体结构 。本研究的目的是探讨 NO 激活血蛋白可溶性鸟苷酸环化酶的机制

Biochem/physiol Actions

丁基异腈与细胞色素 P450 中血红素的三价铁和二价铁形成络合物

Other Notes

可能形成浑浊和/或沉淀,对纯度无影响。


pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

69.8 °F - closed cup

flash_point_c

21 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Robert D Smith et al.
Biochemistry, 49(24), 4977-4986 (2010-05-21)
Crystal structures of methyl, ethyl, propyl, and butyl isocyanide bound to sperm whale myoglobin (Mb) reveal two major conformations. In the in conformer, His(E7) is in a "closed" position, forcing the ligand alkyl chain to point inward. In the out
Alessandra Pesce et al.
Methods in enzymology, 436, 303-315 (2008-02-02)
Protein matrix cavities and extended tunnels can effectively channel substrates and products to and from active sites in enzymes. Substrate and product channeling can enhance catalytic efficiency by reducing the intramolecular diffusion times to and from reaction centers. Moreover, protected
Y Imai et al.
Biochimica et biophysica acta, 1207(1), 49-57 (1994-07-20)
Thr-303 to Lys-mutated P-450 2E1, as well as Thr-301 to Lys-mutated P-450 2C2, had absorption spectra characteristic of a nitrogenous ligand-bound form of P-450, such as the pyridine complex of P-450 2E1; (i) in the ferric state, the red-shifted Soret



全球贸易项目编号

货号GTIN
133280-5G04061836825195
133280-1G04061838729408