133302
环己基异腈
98%
别名:
异氰环己烷
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关于此项目
线性分子式:
C6H11NC
化学文摘社编号:
分子量:
109.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-238-7
Beilstein/REAXYS Number:
3662332
MDL number:
Assay:
98%
Form:
liquid
Quality Segment
assay
98%
form
liquid
refractive index
n20/D 1.45 (lit.)
density
0.878 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
[C-]#[N+]C1CCCCC1
InChI
1S/C7H11N/c1-8-7-5-3-2-4-6-7/h7H,2-6H2
InChI key
XYZMOVWWVXBHDP-UHFFFAOYSA-N
General description
异氰环已烷与乙炔二羧酸二甲酯反应，得到环戊烯并[b]吡啶衍生物、氮杂螺壬三烯衍生物和氮杂双环壬三烯的混合物。它与乙炔二羧酸二烷基酯反应形成1:1中间产物，该产物易于添加1-苄基靛红和色氨酮，得到高度官能化的新型不饱和γ-螺亚胺内酯。
Application
- 配位化学中的异氰化物：对混合“2 + 1”三羰基二硫代氨基甲酸酯复合物的研究强调了环己基异氰酸酯作为一种有效的单齿配体的作用，有助于利用Re、Tc和Re同位素促进放射性药物应用（Shegani et al., 2021）。
- 有机合成试剂在血管治疗中的应用：本文讨论了环己基异氰酸酯在修饰内源性大麻素系统中的应用，强调了其通过生化途径调节高血压等疾病的治疗潜力（Baranowska-Kuczko et al., 2021）。
- 染料脱色的化学工艺优化：环己基异氰酸酯在用于纺织染料脱色的酶的共价固定化中至关重要，证明其在环境化学和与污染控制相关的工业应用中具有实用性（Salami et al., 2018）。
- 在纳米纤维素改性中的应用：通过促进温度响应聚合物与纤维素纳米原纤维的共价附着，增强了用于智能纺织品和响应材料的材料性能，证明了环己基异氰酸酯在纳米技术中的多功能性（Khine et al., 2018）。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Structure and Thermal Isomerization of the Adducts Formed in the Reaction of Cyclohexyl Isocyanide with Dimethyl Acetylenedicarboxylate1.
Junjappa H, et al.
The Journal of Organic Chemistry, 63(26), 9801-9805 (1998)
Synthesis of some novel ?-spiroiminolactones from reaction of cyclohexyl isocyanide and dialkyl acetylene dicarboxylates with 1-benzylisatin and tryptanthrine.
Azizian J, et al.
Synthetic Communications, 33(3), 387-391 (2003)
Ghasem Marandi
Combinatorial chemistry & high throughput screening, 21(4), 298-301 (2018-04-18)
The reaction of cyclohexylisocyanide and 2-aminopyridine-3- carboxylic acid in the presence of benzaldehyde derivatives in ethanol led to 3-(cyclohexylamino)-2- arylimidazo[1,2-a]pyridine-8-carboxylic acids in high yields. In a three component condensation reaction, isocyanide reacts with 2-aminopyridine-3-carboxylic acid and aromatic aldehydes without any
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 133302-5G | 04061838729446 |
| 133302-1G | 04061838729439 |