13468
2-苯基-1,3-二氧六环-5-醇
mixture of cis and trans, ≥97.0% (HPLC)
别名:
1,3-O-亚苄基甘油
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
经验公式（希尔记法）:
C10H12O3
化学文摘社编号:
分子量:
180.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-963-7
Beilstein/REAXYS Number:
84059
MDL number:
Assay:
≥97.0% (HPLC)
Form:
powder
Quality Level
assay
≥97.0% (HPLC)
form
powder
functional group
ether, hydroxyl, phenyl
storage temp.
2-8°C
SMILES string
OC1COC(OC1)c2ccccc2
InChI
1S/C10H12O3/c11-9-6-12-10(13-7-9)8-4-2-1-3-5-8/h1-5,9-11H,6-7H2
InChI key
BWKDAAFSXYPQOS-UHFFFAOYSA-N
General description
顺式-2-苯基-1,3-二恶烷-5-醇与三苯基膦-四溴化碳反应,生成 顺式-4-溴甲基-2-苯基-1,3-二氧戊环、其 反式-非对映异构体和 反式-5-溴-2-苯基-1,3-二恶烷。
Application
2-苯基-1,3-二恶烷-5-醇可用作合成5-苄氧基1,3-二恶烷-2-酮（甘油单体的碳酸盐）的起始材料。其可在存在锡(II) 2--己酸乙酯(Sn(oct)2)的情况下，与ε己内酯开环聚合。
2-苯基-1,3-二恶烷-5-醇被用作起始试剂以合成甘油碳酸酯单体，即5-苄氧基-1,3-二恶烷-2-酮，该单体与ε-己内酯反应可形成共聚物。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Nucleophilic substitution in glycerol derivatives. Part VI. Halogenodeoxygenation of 2-phenyl-1, 3-dioxan-5-ol to give 1, 3-dioxans and 1, 3-dioxolans.
Aneja R and Davies AP.
Journal of the Chemical Society. Perkin Transactions 1, 141-145 (1974)
Poly (carbonate ester) s based on units of 6-hydroxyhexanoic acid and glycerol.
Wolinsky JB, et al.
Macromolecules, 40(20), 7065-7068 (2007)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 613560-25MG | 04055977263541 |
| 323497-100MG | 04061833279380 |
| 323497-250MG | 04061826708736 |
| 13468-1G-F | 04061838730176 |
| 13468-1KG-R | 04061838730183 |
| 13468-6X1KG-R | 04061834411130 |
| 13468-5G-F | 04061833020739 |
| 13468-2.5KG-R | 04061838730190 |