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关于此项目
线性分子式:
BF3 · MeOH
化学文摘社编号:
分子量:
99.85
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3611499
Concentration:
49-53% ( by NaOH, titration), 50% w/w in methanol
Form:
liquid
vapor pressure
19.5 mmHg ( 20 °C)
Quality Level
form
liquid
autoignition temp.
788 °F
reaction suitability
core: boron, reagent type: Lewis acid, reagent type: catalyst
concentration
49-53% ( by NaOH, titration), 50% w/w in methanol
technique(s)
gas chromatography (GC): suitable
bp
59 °C/4 mmHg
density
1.203 g/mL at 25 °C
functional group
hydroxyl
storage temp.
2-8°C
SMILES string
CO.FB(F)F
InChI
1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
InChI key
JBXYCUKPDAAYAS-UHFFFAOYSA-N
Application
用于盐酸哌醋甲酸的气相色谱分析的试剂。Cl2CHCO2H 的替代物,用于合成富嘌呤低聚物。
路易斯酸用于缩酮和烯醇醚与叔丁基过氧化氢反应制备成对双过氧化物。用于胺的温和脱乙酰反应的试剂。
路易斯酸用于缩酮和烯醇醚与叔丁基过氧化氢反应制备成对双过氧化物。用于胺的温和脱乙酰反应的试剂。
Packaging
推荐将25毫升安全/密封™瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1 - STOT SE 3
target_organs
Eyes,Central nervous system, Kidney, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
49.5 °F
flash_point_c
9.7 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Boron trifluoride-methanol complex as a non-depurinating detritylating agent in DNA synthesis.
M J Mitchell et al.
Nucleic acids research, 18(17), 5321-5321 (1990-09-11)
Tetrahedron Letters, 44, 2301-2301 (2003)
Synthesis, 2215-2215 (2005)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 134821-1L | 04061838730299 |
| 134821-50ML | 04061838730329 |
| 134821-4X25ML | 04061838730312 |
| 134821-250ML | 04061838730305 |



