134848
三苯基甲醇
97%
别名:
三苯甲醇, 羟基三苯基甲烷
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关于此项目
线性分子式:
(C6H5)3COH
化学文摘社编号:
分子量:
260.33
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-988-5
Beilstein/REAXYS Number:
1460837
MDL number:
产品名称
三苯基甲醇, 97%
InChI key
LZTRCELOJRDYMQ-UHFFFAOYSA-N
InChI
1S/C19H16O/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H
SMILES string
OC(c1ccccc1)(c2ccccc2)c3ccccc3
assay
97%
form
solid
bp
360 °C (lit.)
mp
160-163 °C (lit.)
solubility
dioxane: soluble 100 mg/mL, clear, colorless to faintly yellow
functional group
hydroxyl
phenyl
Quality Level
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Application
三苯基甲醇可用于合成pyrylogen的双电子还原产物。
General description
三苯基甲醇可与三苯基氧化膦形成1：1分子络合物。它是甲醇和二甲基亚砜的特定笼形主体，并形成笼型包合物。在高氯酸存在下，它能被9,10-二氢-10-甲基吖啶还原为三苯甲烷。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Steiner
Acta crystallographica. Section C, Crystal structure communications, 56 (Pt 8), 1033-1034 (2000-08-16)
In the crystalline 1:1 molecular complex of triphenylmethanol (TPMeOH) and triphenylphosphine oxide (TPPO), C(19)H(16)O. C(18)H(15)OP, molecular dimers are formed which are linked by O-H. O=P hydrogen bonds. The dimers are aligned by sixfold phenyl embraces to form columns. The structure
Tamer T El-Idreesy et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 9(6), 796-800 (2010-05-12)
The first synthesis of the two-electron reduction product of a pyrylogen is reported. The magnitude of the experimentally determined disproportionation constant for a pyrylogen radical cation was used to advantage in order to provide compelling evidence for formation of this
Efficient Reduction of Triphenylmethanol to Triphenylmethane by 9, l0-Dihydro-10-methylacridine in the Presence of Perchloric Acid.
Ishikawa M, et al.
Chemical Society, Analytical Methods Committee, Analyst, 62, 3754-3756 (1989)
Specific entrapment of methanol and dimethyl sulphoxide (DMSO) by a simple host compound (triphenylmethanol). Crystal structures of the Ph3COH? MeOH (1: 1) and Ph3COH? DMSO (2: 1) clathrate inclusion complexes.
Weber E, et al.
Journal of the Chemical Society. Chemical Communications, 17, 1195-1197 (1989)
Corinne Nguyen et al.
Journal of medicinal chemistry, 49(14), 4183-4195 (2006-07-11)
We report the discovery of novel uracil-based acyclic compounds as inhibitors of deoxyuridine 5'-triphosphate nucleotidohydrolase (dUTPase), an enzyme involved in nucleotide metabolism that has been identified as a promising target for the development of antimalarial drugs. Compounds were assayed against
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