135623
草酸二甲酯
ReagentPlus®, 99%
别名:
Methyl oxalate
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关于此项目
线性分子式:
CH3OCOCOOCH3
化学文摘社编号:
分子量:
118.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-053-6
Beilstein/REAXYS Number:
1071744
MDL number:
产品名称
草酸二甲酯, ReagentPlus®, 99%
InChI key
LOMVENUNSWAXEN-UHFFFAOYSA-N
InChI
1S/C4H6O4/c1-7-3(5)4(6)8-2/h1-2H3
SMILES string
COC(=O)C(=O)OC
product line
ReagentPlus®
assay
99%
form
powder
refractive index
n20/D 1.39 (lit.)
bp
163.5 °C (lit.)
mp
50-54 °C (lit.)
solubility
ethanol: soluble 50 mg/mL, clear to very slightly hazy, colorless
density
1.148 g/mL at 25 °C (lit.)
functional group
ester
Quality Level
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Application
草酸二甲酯（DMO）被用作直接氧化燃料电池中的替代燃料。DMO被用于研究在惰性气体低温基质中分离所得DMO的IR光谱。
General description
草酸二甲酯经过 Cu/SiO2 催化的氢化反应，得到乙二醇。它经过Ag/SiO2 催化的选择性气相加氢反应，得到相应的醇。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
Molecular structure and infrared spectra of dimethyl oxalate.
Lopes SB, et al.
Physical Chemistry Chemical Physics, 4(6), 1014-1020 (2002)
A1h NMR Pulse Gradient Spin-Echo (PGSE) Mass Transport Study of Dimethyl Oxalate and Ethylene Glycol: New Fuels for the DOFC.
Suarez-Gustave S, et al.
Electrochemical and Solid-State Letters, 12(3), 525-528 (2000)
Chao Wen et al.
Chemical communications (Cambridge, England), 49(45), 5195-5197 (2013-05-02)
The variation of the supports on the Cu/SiO2 catalyst plays an important role in the catalytic performance for hydrogenation of dimethyl oxalate. The loss of silica in the form of tetramethoxysilane from the support under the reaction conditions is responsible
Anyuan Yin et al.
Chemical communications (Cambridge, England), 46(24), 4348-4350 (2010-05-14)
Ag/SiO(2) prepared by a sol-gel process is highly effective for selective gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. The catalysts are of great potential as industrially viable and novel catalysts for the production of methyl glycolate and ethylene glycol.
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