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线性分子式:
(CH3)2NCSCl
化学文摘社编号:
分子量:
123.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-468-5
Beilstein/REAXYS Number:
635823
MDL number:
产品名称
二甲氨基硫代甲酰氯, 97%
InChI key
PHWISQNXPLXQRU-UHFFFAOYSA-N
InChI
1S/C3H6ClNS/c1-5(2)3(4)6/h1-2H3
SMILES string
CN(C)C(Cl)=S
assay
97%
form
solid
bp
90-95 °C/0.5 mmHg (lit.)
mp
39-43 °C (lit.)
solubility
chloroform: soluble 100 mg/mL, clear to very slightly hazy, very faintly yellow
functional group
amine
chloro
storage temp.
2-8°C
Quality Level
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Application
二甲氨基硫代甲酰氯被用于吡啶-N-氧化物的化学选择性脱氧反应。 它被用于合成 (±)-硫代胡桐素A。它被用作二甲氨基硫代甲酸酯合成中的起始试剂。
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
A synthesis of (?)-thia-calanolide A, its resolution and in vitro biological evaluation.
Chopade AU, et al. et al.
Arabian Journal of Chemistry (2012)
D K Barma et al.
Organic letters, 5(25), 4755-4757 (2003-12-05)
Dimethylthiocarbamates (DMTCs), prepared from the corresponding alcohols using commercial dimethylthiocarbamoyl chloride, are spectrally simple, achiral, and nonpolar. DMTCs are moderately to highly stable to a wide range of reagents and conditions including metal hydrides, hydroboration, ylides, NaOH, HCl, organolithiums, Grignards
Journal of Heterocyclic Chemistry, 44, 487-487 (2007)
Harley D Betts et al.
Molecules (Basel, Switzerland), 25(19) (2020-10-07)
Silver(I)-based coordination polymers or metal-organic frameworks (MOFs) display useful antibacterial properties, whereby distinct materials with different bonding can afford control over the release of silver(I) ions. Such silver(I) materials are comprised of discrete secondary building units (SBUs), and typically formed
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