135917
奎宁环 盐酸盐
97%
别名:
1-氮杂双环[2.2.2]辛烷 盐酸盐
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关于此项目
经验公式（希尔记法）:
C7H13N · HCl
化学文摘社编号:
分子量:
147.65
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
254-682-1
Beilstein/REAXYS Number:
3675063
MDL number:
Assay:
97%
Form:
solid
Quality Level
InChI key
BZLBBZLOMXKMTA-UHFFFAOYSA-N
InChI
1S/C7H13N.ClH/c1-4-8-5-2-7(1)3-6-8;/h7H,1-6H2;1H
SMILES string
Cl[H].C1CN2CCC1CC2
assay
97%
form
solid
mp
>300 °C (lit.)
General description
Quinuclidine stabilises the group 13 trihydrides, particularly for use in chemical vapour deposition techniques.
Application
Quinuclidine hydrochloride was used in the synthesis of quinuclidine adducts with group 13 trihydride molecules, MH3 (M = B, Al) and their structure elucidation by gas-phase electron diffraction and quantum chemical calculations. It was used to investigate series of organic hydrochloride salts by solid-state 35Cl and 37Cl NMR spectroscopy.
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
High-field chlorine NMR spectroscopy of solid organic hydrochloride salts: a sensitive probe of hydrogen bonding environment.
Bryce DL, et al.
The Journal of Physical Chemistry A, 105(45), 10413-10421 (2001)
Derek A Wann et al.
Dalton transactions (Cambridge, England : 2003), (17)(17), 1687-1696 (2007-04-20)
The structure of quinuclidine, HC(CH(2)CH(2))(3)N, has been re-investigated by quantum chemical calculations and by gas-phase electron diffraction (GED). The GED data, together with published rotational constants, have been analysed using the SARACEN method to determine the most reliable structure (r(h1))
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