产品名称
对氯苯氯甲基硫醚, 97%
InChI key
XPJUCMIJGVAEGF-UHFFFAOYSA-N
InChI
1S/C7H6Cl2S/c8-5-10-7-3-1-6(9)2-4-7/h1-4H,5H2
SMILES string
ClCSc1ccc(Cl)cc1
assay
97%
form
liquid
refractive index
n20/D 1.6065 (lit.)
bp
128-129 °C/12 mmHg (lit.)
density
1.348 g/mL at 25 °C (lit.)
functional group
chloro
thioether
storage temp.
2-8°C
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Application
Chloromethyl 4-chlorophenyl sulfide was used to study the solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative in a wide range of hydroxylic solvents. It was used as starting reagent in the synthesis of (4-chlorophenylthio) methyl acetate. It was used as alkylating reagent in microwave-assisted synthesis of 2-amino-imidazo[1,2-a]pyridine derivatives.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
No data available
flash_point_c
No data available
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
A new approach to the synthesis of 2-aminoimidazo [1, 2-a]pyridine derivatives through microwave-assisted N-alkylation of 2-halopyridines.
Vega JA, et al.
Tetrahedron, 55(8), 2317-2326 (1999)
Synthesis of α-Haloalkyl Esters from α-Arylthioalkyl Esters.
Benneche T, et al.
Acta Chemica Scandinavica, 43, 74-77 (1988)
Dennis N Kevill et al.
Current organic chemistry, 16(12), 1502-1511 (2012-06-20)
The specific rates of solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative have been determined at 0.0 °C in a wide range of hydroxylic solvents, including several containing a fluroalcohol. Treatment in terms of a two-term Grunwald-Winstein equation
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