方案
97%
表单
liquid
折射率
n20/D 1.6065 (lit.)
沸点
128-129 °C/12 mmHg (lit.)
密度
1.348 g/mL at 25 °C (lit.)
官能团
chloro
thioether
储存温度
2-8°C
SMILES字符串
ClCSc1ccc(Cl)cc1
InChI
1S/C7H6Cl2S/c8-5-10-7-3-1-6(9)2-4-7/h1-4H,5H2
InChI key
XPJUCMIJGVAEGF-UHFFFAOYSA-N
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应用
Chloromethyl 4-chlorophenyl sulfide was used to study the solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative in a wide range of hydroxylic solvents. It was used as starting reagent in the synthesis of (4-chlorophenylthio) methyl acetate. It was used as alkylating reagent in microwave-assisted synthesis of 2-amino-imidazo[1,2-a]pyridine derivatives.
警示用语:
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
No data available
闪点(°C)
No data available
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
A new approach to the synthesis of 2-aminoimidazo [1, 2-a]pyridine derivatives through microwave-assisted N-alkylation of 2-halopyridines.
Vega JA, et al.
Tetrahedron, 55(8), 2317-2326 (1999)
Dennis N Kevill et al.
Current organic chemistry, 16(12), 1502-1511 (2012-06-20)
The specific rates of solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative have been determined at 0.0 °C in a wide range of hydroxylic solvents, including several containing a fluroalcohol. Treatment in terms of a two-term Grunwald-Winstein equation
Synthesis of α-Haloalkyl Esters from α-Arylthioalkyl Esters.
Benneche T, et al.
Acta Chemica Scandinavica, 43, 74-77 (1988)
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