136727
3-氯苄溴
97%
别名:
α-溴-3-氯甲苯
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关于此项目
线性分子式:
ClC6H4CH2Br
化学文摘社编号:
分子量:
205.48
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-171-0
Beilstein/REAXYS Number:
636504
MDL number:
产品名称
3-氯苄溴, 97%
InChI key
LZIYAIRGDHSVED-UHFFFAOYSA-N
InChI
1S/C7H6BrCl/c8-5-6-2-1-3-7(9)4-6/h1-4H,5H2
SMILES string
Clc1cccc(CBr)c1
assay
97%
form
liquid
refractive index
n20/D 1.588 (lit.)
bp
109-110 °C/12 mmHg (lit.)
density
1.565 g/mL at 25 °C (lit.)
functional group
bromo
chloro
Quality Level
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Application
3-Chlorobenzyl bromide was used in the synthesis of symmetrical and unsymmetrical benzyl thioethers. It was used as starting reagent during the synthesis of 1-(3-chlorobenzyl)-2-(pyrrolidin-1-ylmethyl)-1H-benzimidazole dihydrochloride.
General description
3-Chlorobenzyl bromide reacts with aminoethanol and NaH to yield aminoethyl 3-chlorobenzyl ether.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Selective inactivation of monoamine oxidase B by aminoethyl 3-chlorobenzyl ether.
Ding CZ and Silverman RB.
Bioorganic & Medicinal Chemistry, 3(10), 2077-2078 (1993)
Convenient and robust one-pot synthesis of symmetrical and unsymmetrical benzyl thioethers from benzyl halides using thiourea.
Eccles KS, et al.
ARKIVOC (Gainesville, FL, United States), ix, 216-218 (2010)
Jason Z Vlahakis et al.
Bioorganic & medicinal chemistry, 21(21), 6788-6795 (2013-09-12)
Several analogs based on the lead structure of 1-(4-chlorobenzyl)-2-(pyrrolidin-1-ylmethyl)-1H-benzimidazole (clemizole) were synthesized and evaluated as novel inhibitors of heme oxygenase (HO). Many of the compounds were found to be potent and highly selective for the HO-2 isozyme (constitutive), and had
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