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经验公式(希尔记法):
C5H4ClNO
化学文摘社编号:
分子量:
129.54
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
240-909-1
MDL number:
Assay:
98%
InChI key
CLNNBQDAAGDAHI-UHFFFAOYSA-N
InChI
1S/C5H4ClNO/c6-4-2-1-3-5(8)7-4/h1-3H,(H,7,8)
SMILES string
Oc1cccc(Cl)n1
assay
98%
mp
128-130 °C (lit.)
Quality Level
General description
6-chloro-2-hydroxypyridine undergoes melt reaction with Os2(O2CCH3)4CI2 at 145°C to yield Os2CI4(chp) and Os2Cl(chp)4.
Application
6-chloro-2-hydroxypyridine was used to study the synthesis, electrochemistry, spectroscopic properties and X-ray crystal structure of Os2Cl(chp)4 (chp = 6-chloro-2- hydroxypyridinate) complex.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Preparation and structural characterization of Os2Cl4(chp)2(L)(chp= 6-chloro-2-hydroxypridinato; L= water, pyridine): a new class of M2X4 (LL)2 complexes possessing an eclipsed conformation
Cotton F, et al.
Inorganic Chemistry, 25(10), 1589-1594 (1986)
Synthesis, spectroscopy, and x-ray structure of chlorotetrakis (6-chloro-2-hydroxypyridinato) diosmium: an unusual Os25+ complex with a polar arrangement of 6-chloro-2-hydroxypyridinato ligands and one axial chloride.
Cotton F, et al.
Inorganic Chemistry, 25(10), 1585-1589 (1986)
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