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136905

4-甲氧基苄醇

Name: 4-甲氧基苄醇
Brand: ALDRICH

98%

别名:

对甲氧基苄醇, 对茴香醇, 茴香醇

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关于此项目

线性分子式:

CH₃OC₆H₄CH₂OH

化学文摘社编号:

105-13-5

分子量:

138.16

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848301

EC Number:

203-273-6

Beilstein/REAXYS Number:

636654

MDL number:

MFCD00004653

Assay:

98%

Form:

solid

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属性

Quality Level

100

assay

98%

form

solid

refractive index

n20/D 1.544 (lit.)

bp

259 °C (lit.)

mp

22-25 °C (lit.)

solubility

alcohol: freely soluble, diethyl ether: freely soluble, water: insoluble

density

1.113 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

COc1ccc(CO)cc1

InChI

1S/C8H10O2/c1-10-8-4-2-7(6-9)3-5-8/h2-5,9H,6H2,1H3

InChI key

MSHFRERJPWKJFX-UHFFFAOYSA-N

说明

General description

4-甲氧基苄醇通常用作保护醇和酚上羟基的试剂。4-甲氧基苄醇与气相二氧化硅纳米颗粒的硅烷醇基缩合，生成改性二氧化硅纳米颗粒。它由黄素-锌(II)-轮环藤宁配合物催化发生光氧化，生成相应的苯甲醛。

Application

4-甲氧基苄醇用于研究4-甲氧基苄醇到对茴香醛的光催化氧化反应。

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pictograms

GHS07

signalword

Warning

hcodes

H315,H317,H319

pcodes

P261 - P264 - P272 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B

存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

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Triplet state of 4-methoxybenzyl alcohol chemisorbed on silica nanoparticles.

Valeria B Arce et al.

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 11(6), 1032-1040 (2012-03-17)

The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation

Selective photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde in organic-free water in a continuous annular fixed bed reactor.

Loddo V, et al.

International Journal of Chemical Reactor Engineering, 5(1) (2007)

Catalytic photooxidation of 4-methoxybenzyl alcohol with a flavin-zinc(II)-cyclen complex.

Radek Cibulka et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 10(24), 6224-6231 (2004-10-16)

Flavin-zinc(II)-cyclen 10 contains a covalently linked substrate binding site (zinc(II)-cyclen) and a chromophore unit (flavin). Upon irradiation, compound 10 effectively oxidizes 4-methoxybenzyl alcohol (11-OCH3) to the corresponding benzaldehyde both in water and in acetonitrile. In the presence of air, the

全球贸易项目编号

货号	GTIN
136905-100G	04061838731524
136905-500G	04061838731531
136905-5G	04061838731548