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137286

5-溴水杨醛

Name: 5-溴水杨醛
Brand: ALDRICH

98%

别名:

5-溴-2-羟基苯甲醛

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关于此项目

线性分子式:

BrC₆H₃-2-(OH)CHO

化学文摘社编号:

1761-61-1

分子量:

201.02

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848318

EC Number:

217-167-2

Beilstein/REAXYS Number:

774710

MDL number:

MFCD00003330

Assay:

98%

Form:

powder

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属性

Quality Level

200

assay

98%

form

powder

mp

102-106 °C (lit.)

functional group

aldehyde, bromo

SMILES string

Oc1ccc(Br)cc1C=O

InChI

1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H

InChI key

MKKSTJKBKNCMRV-UHFFFAOYSA-N

说明

General description

5-溴水杨醛与1,2-双(4-氯-2-氨基苯氧基)乙烷反应，生成席夫碱配体1,2-双(2-(5-溴-2-羟基苯甲醛亚胺)-4-氯苯氧基)乙烷。这是合成二芳基氨基取代的N-甲基四氢salen配体的起始试剂。

5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。

Application

5-溴水杨醛可用于聚对苯二甲酸乙二醇酯（PET）薄膜和PET支架中胺定量过程中的化学衍生化。

存储类别

11 - Combustible Solids

ppe

dust mask type N95 (US), Eyeshields, Gloves

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H302,H315,H317,H411

pcodes

P261 - P264 - P273 - P280 - P301 + P312 - P302 + P352

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

0000516017

0000516023

SDBB5786

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Synthesis and characterization of 1,2-bis(2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy)ethane and its metal complexes: an experimental, theoretical, electrochemical, antioxidant and antibacterial study.

Salih Ilhan et al.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 632-642 (2013-10-08)

A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied

Investigations on the photochromic properties of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone.

L N Corîci et al.

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 16(6), 946-953 (2017-04-27)

The network of chemical reactions of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone (BHBC) when subjected to light and different pH values has been investigated. The pH dependent species involved in the chemical network have been identified and characterized by NMR and UV-VIS spectroscopy. Direct pH

Redox-active tetrahydrosalen (salan) complexes of titanium.

Mauricio Quiroz-Guzman et al.

Dalton transactions (Cambridge, England : 2003), 40(43), 11458-11468 (2011-09-22)

A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Hartwig-Buchwald amination of the tert-butyldimethylsilyl-protected 5-bromo-N-methylsalan ligand. Reaction of (An2N)LH(2) or its bromo analogue with Ti(O(i)Pr)(4)

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全球贸易项目编号

货号	GTIN
137286-25G	04061838731708
137286-100G	04061838731692