137286
5-溴水杨醛
98%
别名:
5-溴-2-羟基苯甲醛
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关于此项目
线性分子式:
BrC6H3-2-(OH)CHO
化学文摘社编号:
分子量:
201.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-167-2
Beilstein/REAXYS Number:
774710
MDL number:
Assay:
98%
Form:
powder
InChI key
MKKSTJKBKNCMRV-UHFFFAOYSA-N
InChI
1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H
SMILES string
Oc1ccc(Br)cc1C=O
assay
98%
form
powder
Quality Level
functional group
aldehyde, bromo
General description
5-溴水杨醛与1,2-双(4-氯-2-氨基苯氧基)乙烷反应，生成席夫碱配体1,2-双(2-(5-溴-2-羟基苯甲醛亚胺)-4-氯苯氧基)乙烷。这是合成二芳基氨基取代的N-甲基四氢salen配体的起始试剂。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
Application
5-溴水杨醛可用于聚对苯二甲酸乙二醇酯（PET）薄膜和PET支架中胺定量过程中的化学衍生化。
存储类别
11 - Combustible Solids
ppe
dust mask type N95 (US), Eyeshields, Gloves
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B
Effect of Surface Modification by Ammonia Plasma on Vascular Graft: PET Film and PET Scaffold.
Oteyaka MO, et al.
Acta Physica Polonica A, 121(1), 125-125 (2012)
Mauricio Quiroz-Guzman et al.
Dalton transactions (Cambridge, England : 2003), 40(43), 11458-11468 (2011-09-22)
A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Hartwig-Buchwald amination of the tert-butyldimethylsilyl-protected 5-bromo-N-methylsalan ligand. Reaction of (An2N)LH(2) or its bromo analogue with Ti(O(i)Pr)(4)
Masahito Yoshida et al.
Chemical & pharmaceutical bulletin, 68(3), 220-226 (2019-10-05)
This study demonstrates the structure-activity relationship of Col-003, a potent collagen-heat-shock protein 47 (Hsp47) interaction inhibitor. Col-003 analogues were successfully synthesized by Pd(0)-catalyzed cross-coupling reactions of 5-bromosalicylaldehyde derivatives with alkyl-metal species, and the inhibitory activities of the synthetic analogues were
Synthesis, characterization, and cytotoxic activity of triphenyltin complexes of N-(5-bromosalicylidene)-?-amino acids
Yao Y, et al.
Main Group Metal Chemistry, 40, 93-99 (2017)
Salih Ilhan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 632-642 (2013-10-08)
A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied
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