137995
1,2,3-三甲氧基苯
98%
别名:
邻苯三酚三甲醚
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关于此项目
线性分子式:
C6H3(OCH3)3
化学文摘社编号:
分子量:
168.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-207-2
Beilstein/REAXYS Number:
1910422
MDL number:
Assay:
98%
Form:
chunks
产品名称
1,2,3-三甲氧基苯, 98%
InChI key
CRUILBNAQILVHZ-UHFFFAOYSA-N
InChI
1S/C9H12O3/c1-10-7-5-4-6-8(11-2)9(7)12-3/h4-6H,1-3H3
SMILES string
COc1cccc(OC)c1OC
assay
98%
form
chunks
bp
241 °C (lit.)
mp
43-47 °C (lit.)
density
1.112 g/mL at 25 °C (lit.)
Quality Level
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Application
1,2,3-三甲氧基苯用于研究溶剂对光致电子转移反应的影响。
General description
1,2,3-三甲氧基苯与2,4-二氨基-5-(羟甲基)嘧啶发生缩合反应，得到2,4-二氨基-5-(2,3,4-三甲氧基苄基)嘧啶。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Zhangjie Shi et al.
Journal of the American Chemical Society, 126(19), 5964-5965 (2004-05-13)
A gold-catalyzed cyclialkylation of electron-rich arenes with tethered epoxides afforded 3-chromanols stereospecifically.
Romelo Gibe et al.
Chemical communications (Cambridge, England), (14)(14), 1550-1551 (2002-08-23)
Nicholas reactions of the p-phenyl linked bis(propargyl acetate) complex (3a) with electron rich arenes give cyclophanetetrayne complexes (5). The use of bis(propargyl ether) complex (8) with (3a) allows formation of a mixed cyclophanetetrayne complex (9), and in addition gives retro-Nicholas/intramolecular
A Stuart et al.
Journal of medicinal chemistry, 26(5), 667-673 (1983-05-01)
A new route to 2,4-diamino-5-(4-hydroxybenzyl)pyrimidines has been developed that involves the condensation of 2,4-diamino-5-(hydroxymethyl)pyrimidine with phenols in acidic medium. The use of phenol and its 2,6-dialkyl derivatives produces 5-(4-hydroxybenzyl)pyrimidines exclusively. However, 2,6-dimethoxyphenol produces a mixture of 5-(3-hydroxy-2,4-dimethoxybenzyl)- and 5-(4-hydroxy-3,5-dimethoxybenzyl)pyrimidines. The
Jian Zhi Hu et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 198(1), 105-110 (2009-02-28)
An isotropic-anisotropic shift 2D correlation spectroscopy is introduced that combines the advantages of both magic angle turning (MAT) and magic angle hopping (MAH) technologies. In this new approach, denoted DMAT for "discrete magic angle turning", the sample rotates clockwise followed
Ramjee Kandel et al.
Dalton transactions (Cambridge, England : 2003), 48(33), 12512-12521 (2019-08-01)
Phosphaamidine metal complexes Rh2Cl2[Ph2PC(Ph)[double bond, length as m-dash]NPh]2μ-CO (1), RuCl2[Ph2PC(Ph)[double bond, length as m-dash]N(Ph)]2 (2), [Rh{iPr2PC(Ph)[double bond, length as m-dash]NiPr}(COD)]BF4 (3), and RuCl2[iPr2PC(Ph)[double bond, length as m-dash]NiPr](DMSO)2 (4) are prepared by combining phosphaamidines Ph2P-C(Ph)[double bond, length as m-dash]NPh and iPr2P-C(Ph)[double
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