139122
异丁酰氯
98%
别名:
2-丙基碳酰氯, 2-甲基丙酰氯, 2-甲基丙酸氯化物, 异丁酰氯, 异丙基羰基氯, 氯异丙基酮
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关于此项目
线性分子式:
(CH3)2CHCOCl
化学文摘社编号:
分子量:
106.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-194-1
Beilstein/REAXYS Number:
605393
MDL number:
产品名称
异丁酰氯, 98%
InChI key
DGMOBVGABMBZSB-UHFFFAOYSA-N
InChI
1S/C4H7ClO/c1-3(2)4(5)6/h3H,1-2H3
SMILES string
CC(C)C(Cl)=O
vapor pressure
0.07 mmHg ( 20 °C)
assay
98%
form
liquid
refractive index
n20/D 1.407 (lit.)
bp
91-93 °C (lit.)
mp
−90 °C (lit.)
density
1.017 g/mL at 25 °C (lit.)
functional group
acyl chloride
Quality Level
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Application
多功能酰化剂，用于 α-氨基酯、核苷和吡咯的酮亚胺衍生物。
异丁酰氯用于合成完全异丁酰胺封端的超支化聚乙烯亚胺，还用于 Echium italicum L 根表皮中紫草素及其酯衍生物的分离和 鉴定，以及用作 α-酮亚胺衍生物的氨基酯类 、核苷类 和吡咯类 通用酰化剂。
General description
异丁酰氯与鸟嘌呤反应生成 N (2)-异丁酰基鸟嘌呤 。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1A
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
46.4 °F - closed cup
flash_point_c
8 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron Letters, 34, 211-211 (1993)
Mathilde Ménard et al.
Biochimica et biophysica acta. General subjects, 1863(2), 332-341 (2018-11-06)
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Lijing Yang et al.
Magnetic resonance in chemistry : MRC, 51(1), 60-64 (2012-11-21)
N(2)-isobutyrylguanine was prepared by treatment of guanine with isobutyryl chloride. Two tautomers, 1,7-dihydro-2-(isobutyroyl)amino-6H-purin-6-one and 1,9-dihydro-2-(isobutyroyl)amino-6H-purin-6-one, were identified in almost 1:1 ratio in dichloromethane-dimethyl sulfoxide (1:1 v/v) by NMR spectroscopy. By using the selective-inversion experiments, enthalpy, entropy, and free energy for activation
Thermoresponsive hyperbranched polyethylenimines with isobutyramide functional groups.
Liu H, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 45(6), 1177-1184 (2007)
Heteroatom Chem., 4, 39-39 (1993)
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