139238
六氟丙酮 三水合物
98%
别名:
全氟丙酮 三水合物, 六氟-2-丙酮 三水合物
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关于此项目
线性分子式:
(CF3)2CO · 3H2O
CAS Number:
分子量:
220.07
Beilstein:
607236
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
87.5 psi ( 21 °C)
质量水平
方案
98%
表单
liquid
折射率
n20/D 1.319 (lit.)
mp
18-21 °C (lit.)
密度
1.579 g/mL at 25 °C (lit.)
官能团
fluoro
ketone
SMILES字符串
[H]O[H].[H]O[H].[H]O[H].FC(F)(F)C(=O)C(F)(F)F
InChI
1S/C3F6O.3H2O/c4-2(5,6)1(10)3(7,8)9;;;/h;3*1H2
InChI key
SNZAEUWCEHDROX-UHFFFAOYSA-N
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一般描述
六氟丙酮三水合物与咪唑 3-氧化物形成 1:1 的结晶性复合物 。
应用
以六氟丙酮三水合物为模型化合物，研究了（丙酮）五氨基钌 (Ⅲ) 钌 (Ⅱ) 配合物的连接异构化动力学和热力学 。在一项研究中用于复溶 α-和 β- 球形红杆菌 和 红色红螺菌 与 细菌叶绿素 a 的多肽。
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
First synthesis of the N (1)-bulky substituted imidazole 3-oxides and their complexation with hexafluoroacetone hydrate.
Mloston G and Jasinski M.
ARKIVOC (Gainesville, FL, United States), 6, 162-175 (2011)
Sung-Won Ha et al.
Biomacromolecules, 7(1), 18-23 (2006-01-10)
Employing high-resolution (13)C solution NMR and circular dichroism (CD) spectroscopic techniques, the distinctive influence of two intimately related hexafluoro solvents, 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) and hexafluoroacetone trihydrate (HFA), on the structural characteristics of Bombyx mori (B. mori) silk fibroin, the chymotrypsin precipitate
Jan Spengler et al.
The Journal of organic chemistry, 73(6), 2311-2314 (2008-02-22)
beta-Hydroxy acids were reacted with hexafluoroacetone and carbodiimides to give carboxy-activated six-membered lactones in good yields. On reaction with amines, the corresponding amides were obtained. We demonstrate the following applications of this protecting/activating strategy: preparation of carboxamides in solution and
Silklike materials constructed from sequences of Bombyx mori silk fibroin, fibronectin, and elastin.
Mingying Yang et al.
Journal of biomedical materials research. Part A, 84(2), 353-363 (2007-07-10)
Two silklike proteins, [TGRGDSPAGG(GAGAGS)3AS]5 (FS5) and [TGRGDSPA-(GVPGV)2GG(GAGAGS)3AS]8 (FES8) were designed to demonstrate the superior performance as biomaterials of silklike proteins. The former protein consists of the crystalline domain sequence, (GAGAGS)n from Bombyx mori silk fibroin and cell-adhesive sequence TGRGDSPA coming
Linkage isomerization reactions of (acetone) pentaammineruthenium (III) and-ruthenium (II) complexes.
Powell DW and Lay PA.
Inorganic Chemistry, 31(17), 3542-3550 (1992)
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