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Merck
CN

139238

六氟丙酮 三水合物

98%

别名:

全氟丙酮 三水合物, 六氟-2-丙酮 三水合物

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关于此项目

线性分子式:
(CF3)2CO · 3H2O
化学文摘社编号:
分子量:
220.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-676-3
Beilstein/REAXYS Number:
607236
MDL number:
Assay:
98%
Form:
liquid
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InChI key

SNZAEUWCEHDROX-UHFFFAOYSA-N

InChI

1S/C3F6O.3H2O/c4-2(5,6)1(10)3(7,8)9;;;/h;3*1H2

SMILES string

[H]O[H].[H]O[H].[H]O[H].FC(F)(F)C(=O)C(F)(F)F

vapor pressure

87.5 psi ( 21 °C)

assay

98%

form

liquid

refractive index

n20/D 1.319 (lit.)

mp

18-21 °C (lit.)

density

1.579 g/mL at 25 °C (lit.)

functional group

fluoro, ketone

Quality Level

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Application

以六氟丙酮三水合物为模型化合物,研究了(丙酮)五氨基钌 (Ⅲ) 钌 (Ⅱ) 配合物的连接异构化动力学和热力学 。在一项研究中用于复溶 α-和 β- 球形红杆菌 红色红螺菌 细菌叶绿素 a 的多肽。

General description

六氟丙酮三水合物与咪唑 3-氧化物形成 1:1 的结晶性复合物

signalword

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品
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分析证书(COA)

Lot/Batch Number

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First synthesis of the N (1)-bulky substituted imidazole 3-oxides and their complexation with hexafluoroacetone hydrate.
Mloston G and Jasinski M.
ARKIVOC (Gainesville, FL, United States), 6, 162-175 (2011)
T Rühl et al.
Amino acids, 27(3-4), 285-290 (2004-11-19)
Hexafluoroacetone was applied as a bidentate protecting and activating agent for the syntheses of RGD-peptide mimetics starting from iminodiacetic acid in solution and on solid phase.
Diwakar M Pawar et al.
The Journal of organic chemistry, 72(6), 2003-2007 (2007-02-17)
Low-temperature 1H and 13C NMR spectra of formic acid (1) showed separate signals for the E and Z conformations in solvents containing a hydrogen bond acceptor, dimethyl ether. The population of E-1 (6.2% in 3:1:1 CHClF2/CHCl2F/(CH3)2O) was larger than that
H Wille et al.
Journal of molecular biology, 259(4), 608-621 (1996-06-21)
The prion protein (PrP) undergoes a profound conformational change when the cellular isoform (PrPC) is converted into the scrapie form (PrPSc). Limited proteolysis of PrPsc produces PrP 27-30 which readily polymerizes into amyloid. To study the structure of PrP amyloid
S Bhattacharjya et al.
Protein science : a publication of the Protein Society, 7(1), 123-131 (1998-03-26)
Riboflavin carrier protein (RCP) plays an important role in transporting vitamin B2 across placental membranes, a process critical for maintenance of pregnancy. Association of the vitamin with the carrier protein ensures optimal bioavailability, facilitating transport. The conformations of three antigenic

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