139238
六氟丙酮 三水合物
98%
别名:
全氟丙酮 三水合物, 六氟-2-丙酮 三水合物
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关于此项目
线性分子式:
(CF3)2CO · 3H2O
化学文摘社编号:
分子量:
220.07
Beilstein:
607236
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
87.5 psi ( 21 °C)
质量水平
方案
98%
表单
liquid
折射率
n20/D 1.319 (lit.)
mp
18-21 °C (lit.)
密度
1.579 g/mL at 25 °C (lit.)
官能团
fluoro
ketone
SMILES字符串
[H]O[H].[H]O[H].[H]O[H].FC(F)(F)C(=O)C(F)(F)F
InChI
1S/C3F6O.3H2O/c4-2(5,6)1(10)3(7,8)9;;;/h;3*1H2
InChI key
SNZAEUWCEHDROX-UHFFFAOYSA-N
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一般描述
六氟丙酮三水合物与咪唑 3-氧化物形成 1:1 的结晶性复合物 。
应用
以六氟丙酮三水合物为模型化合物，研究了（丙酮）五氨基钌 (Ⅲ) 钌 (Ⅱ) 配合物的连接异构化动力学和热力学 。在一项研究中用于复溶 α-和 β- 球形红杆菌 和 红色红螺菌 与 细菌叶绿素 a 的多肽。
警示用语：
Danger
危险分类
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 2 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Linkage isomerization reactions of (acetone) pentaammineruthenium (III) and-ruthenium (II) complexes.
Powell DW and Lay PA.
Inorganic Chemistry, 31(17), 3542-3550 (1992)
First synthesis of the N (1)-bulky substituted imidazole 3-oxides and their complexation with hexafluoroacetone hydrate.
Mloston G and Jasinski M.
ARKIVOC (Gainesville, FL, United States), 6, 162-175 (2011)
C M Davis et al.
The Journal of biological chemistry, 270(11), 5793-5804 (1995-03-17)
Methodology has been developed to reconstitute carotenoids and bacteriochlorophyll alpha with isolated light-harvesting complex I (LHI) polypeptides of both Rhodobacter sphaeroides and Rhodospirillum rubrum. Reconstitution techniques first developed in this laboratory using the LHI polypeptides of R. rubrum, R. sphaeroides
Carlo Guardiani et al.
The journal of physical chemistry. B, 116(18), 5458-5467 (2012-04-24)
Synthetic N-glycosylated CSF114(Glc) and related peptides were proved to be able to recognize specific and high-affinity autoantibodies circulating in blood of relapsing-remitting multiple sclerosis (MS) patients and correlating with disease activity. The effect of these peptides has been linked to
S Bhattacharjya et al.
Protein science : a publication of the Protein Society, 6(5), 1065-1073 (1997-05-01)
A molten globule-like state of hen egg-white lysozyme has been characterized in 25% aqueous hexafluoroacetone hydrate (HFA) by CD, fluorescence, NMR, and H/D exchange experiments. The far UV CD spectra of lysozyme in 25% HFA supports retention of native-like secondary
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