13929
硫氰酸苄酯
≥95.0% (GC)
别名:
硫氰化苄
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关于此项目
线性分子式:
C6H5CH2SCN
化学文摘社编号:
分子量:
149.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-144-2
Beilstein/REAXYS Number:
1859726
MDL number:
Assay:
≥95.0% (GC)
Form:
solid
InChI key
ABNDFSOIUFLJAH-UHFFFAOYSA-N
InChI
1S/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2
SMILES string
N#CSCc1ccccc1
assay
≥95.0% (GC)
form
solid
bp
230-235 °C (lit.)
Quality Level
solubility
diethyl ether: soluble 0.5 g/10 mL, clear to very faintly turbid, colorless to almost colorless
functional group
phenyl, thiocyanate, thioether
storage temp.
2-8°C
General description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Application
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F
flash_point_c
110 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
V Erban et al.
Folia microbiologica, 32(5), 411-416 (1987-01-01)
The localization of anhydrotetracycline oxygenase and glucose-6-phosphate dehydrogenase (EC 1.1.1.49) was studied by determining the enzyme activities in subcellular fractions obtained by differential centrifugation of the mycelia of Streptomyces aureofaciens after lysozyme treatment. Glucose-6-phosphate dehydrogenase was a typical cytoplasmic enzyme
V Bĕhal et al.
Folia microbiologica, 27(2), 102-106 (1982-01-01)
The level of anhydrotetracyline oxygenase (an enzyme catalyzing the penultimate reaction in the biosynthesis of tetracyline) in Streptomyces aureofaciens was substantially influenced by the amount of inorganic phosphate and by the presence of benzyl thiocyanate in the cultivation medium. Phosphate
X M Li et al.
Applied microbiology and biotechnology, 57(5-6), 717-724 (2002-01-10)
Changes in synthesis and abundance of proteins associated with chlortetracycline (CTC) production in Streptomyces aureofaciens were investigated by two-dimensional polyacrylamide gel electrophoresis of proteins pulse-labelled in vivo with L-[35S]methionine. Eleven individual protein spots were selected as being related to formation
J Nayini et al.
Carcinogenesis, 10(3), 509-512 (1989-03-01)
The effect of the dietary organoselenium compound, benzylselenocyanate (BSC) along with its sulphur analogue, benzylthiocynanate (BTC) and sodium selenite (Na2SeO3), on 7,12-dimethylbenz[a]anthracene (DMBA)-induced mammary carcinogenesis was examined in female Sprague-Dawley rats during the initiation phase of carcinogenesis. Semipurified diets containing
L V Trilisenko et al.
Folia microbiologica, 32(5), 402-410 (1987-01-01)
Mycelia of a low- and a high-production strain of Streptomyces aureofaciens were converted into protoplasts and divided into five subcellular fractions in order to localize exopolyphosphatases (EC 3.6.1.11), triphosphatase (EC 3.6.1.25), inorganic diphosphatase (EC 3.6.1.1), apyrase (EC 3.6.1.5) and glucokinase
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