13929
硫氰酸苄酯
≥95.0% (GC)
别名:
硫氰化苄
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线性分子式:
C6H5CH2SCN
化学文摘社编号:
分子量:
149.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-144-2
Beilstein/REAXYS Number:
1859726
MDL number:
Assay:
≥95.0% (GC)
Form:
solid
InChI key
ABNDFSOIUFLJAH-UHFFFAOYSA-N
InChI
1S/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2
SMILES string
N#CSCc1ccccc1
assay
≥95.0% (GC)
form
solid
bp
230-235 °C (lit.)
mp
39-41 °C (lit.), 39-41 °C
solubility
diethyl ether: soluble 0.5 g/10 mL, clear to very faintly turbid, colorless to almost colorless
functional group
phenyl, thiocyanate, thioether
storage temp.
2-8°C
Quality Level
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Application
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
General description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F
flash_point_c
110 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
S Sugie et al.
Japanese journal of cancer research : Gann, 84(8), 865-870 (1993-08-01)
The effects of two aromatic thiocyanates, benzyl isothiocyanate (BITC) and benzyl thiocyanate (BTC), on diethylnitrosamine (DEN)-induced hepatocarcinogenesis were examined in rats. A total of 108 male ACI/N rats, 5 weeks old, were divided into 6 groups (18 rats in each).
[Obstructive cholangiopathy and isothiocyanate].
D W Bleyl et al.
Die Nahrung, 35(7), 783-785 (1991-01-01)
J Novotná et al.
Current microbiology, 31(2), 84-91 (1995-08-01)
Cell protein profiles of submerged cultures of Streptomyces aureofaciens cultivated in the absence or presence of 12 microM benzyl thiocyanate (BT) were analyzed by one-dimensional SDS polyacrylamide gel electrophoresis. Substantial increase in the intensity of the 13, 35, 37, 60
V Bĕhal et al.
Folia microbiologica, 27(2), 102-106 (1982-01-01)
The level of anhydrotetracyline oxygenase (an enzyme catalyzing the penultimate reaction in the biosynthesis of tetracyline) in Streptomyces aureofaciens was substantially influenced by the amount of inorganic phosphate and by the presence of benzyl thiocyanate in the cultivation medium. Phosphate
V Erban et al.
Folia microbiologica, 32(5), 411-416 (1987-01-01)
The localization of anhydrotetracycline oxygenase and glucose-6-phosphate dehydrogenase (EC 1.1.1.49) was studied by determining the enzyme activities in subcellular fractions obtained by differential centrifugation of the mycelia of Streptomyces aureofaciens after lysozyme treatment. Glucose-6-phosphate dehydrogenase was a typical cytoplasmic enzyme
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