13954
苄基三丁基溴化铵
≥99.0%, solid
别名:
Benzyltri-n-butylammonium bromide, Tributylbenzylammonium bromide
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关于此项目
线性分子式:
C6H5CH2N(Br)(CH2CH2CH2CH3)3
化学文摘社编号:
分子量:
356.38
Beilstein:
3776294
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
产品名称
苄基三丁基溴化铵, ≥99.0%
质量水平
方案
≥99.0%
表单
solid
mp
169-175 °C
SMILES字符串
[Br-].CCCC[N+](CCCC)(CCCC)Cc1ccccc1
InChI
1S/C19H34N.BrH/c1-4-7-15-20(16-8-5-2,17-9-6-3)18-19-13-11-10-12-14-19;/h10-14H,4-9,15-18H2,1-3H3;1H/q+1;/p-1
InChI key
UDYGXWPMSJPFDG-UHFFFAOYSA-M
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应用
Benzyltributylammonium bromide can be used:
- As a phase transfer catalyst in the isomerization reactions of cis-4-formyl-2-azetidinones.
- As a hydrogen-bond acceptor in the preparation of deep eutectic solvents, which are used in the isolation of lysozyme from the chicken egg white.
- In the phase transfer glycosylation of novobiocin to yield glucosyl-novobiocin.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Regioselective glycosylation of novobiocin alters activity
Sun G, et al.
Carbohydrate Research, 452(11), 116-121 (2017)
Harish Babu Balaraman et al.
International journal of biological macromolecules, 146, 253-262 (2020-01-10)
The present research investigates on task-specific deep eutectic solvents (TDES) based aqueous two-phase extraction and purification of immunoglobulins by chromatography from quail egg. The synthesis of TDES was accomplished with quaternary ammonium salt as hydrogen bond acceptor (HBA) and glycerol
Development of deep eutectic solvent-based aqueous biphasic system for the extraction of lysozyme
Xu P, et al.
Talanta, 202(11), 1-10 (2019)
Base-Promoted Isomerization of cis-4-Formyl-2-azetidinones: Chemoselective C 4-Epimerization vs Rearrangement to Cyclic Enaminones
Alcaide B, et al.
The Journal of Organic Chemistry, 65(11), 3453-3459 (2000)
F G Riddell et al.
Journal of inorganic biochemistry, 55(4), 279-293 (1994-09-01)
One major problem in using NMR to study halide ions in biological and model biological systems has been to find a contrast reagent to differentiate between halide ions in different compartments. Mn2+ is shown to be a very efficient NMR
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