139661
2,2,2-三氯乙酰亚胺酸甲酯
98%
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关于此项目
线性分子式:
CCl3C(=NH)OCH3
化学文摘社编号:
分子量:
176.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
219-796-8
MDL number:
Assay:
98%
Form:
liquid
产品名称
2,2,2-三氯乙酰亚胺酸甲酯, 98%
InChI key
OGBINJLTBZWRRB-UHFFFAOYSA-N
InChI
1S/C3H4Cl3NO/c1-8-2(7)3(4,5)6/h7H,1H3
SMILES string
COC(=N)C(Cl)(Cl)Cl
assay
98%
form
liquid
refractive index
n20/D 1.478 (lit.)
bp
148-149 °C (lit.)
density
1.425 g/mL at 25 °C (lit.)
functional group
chloro
ether
storage temp.
2-8°C
Quality Level
Application
Methyl 2,2,2-trichloroacetimidate was used as starting material during the synthesis of novel bibenzimidazole oligomers and polymers. It was employed as reagent during the synthesis of 2,2′-bisbenzimidazole-5,5′-dicarboxylic acid.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
165.2 °F - closed cup
flash_point_c
74 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Jun Yin et al.
The Journal of organic chemistry, 70(23), 9436-9446 (2005-11-05)
[Structure: see text]. A simple and mild condensation route for the synthesis of novel bibenzimidazole oligomers and polymers is reported here using methyl 2,2,2-trichloroacetimidate as a key starting material. The dimer, trimer, tetramer, and polymers of bibenzimidazole were synthesized as
A new sequence isomer of AB-polybenzimidazole for high-temperature PEM fuel cells.
Gulledge AL, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 50(2), 306-313 (2012)
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