140066
1,3,5-三溴苯
98%
别名:
1,3,5-三溴苯
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关于此项目
经验公式（希尔记法）:
C6H3Br3
化学文摘社编号:
分子量:
314.80
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-947-3
Beilstein/REAXYS Number:
1858917
MDL number:
Assay:
98%
Form:
powder
产品名称
1,3,5-三溴苯, 98%
InChI key
YWDUZLFWHVQCHY-UHFFFAOYSA-N
InChI
1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H
SMILES string
Brc1cc(Br)cc(Br)c1
assay
98%
form
powder
bp
271 °C (lit.)
mp
117-121 °C (lit.)
functional group
bromo
Quality Level
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General description
- 1,3,5-三溴苯（TBB）作为衍生化步骤的内标，用于通过气相色谱-质谱法测定人血浆和尿液中的氰化物。
- TBB与[60]-和[70]富勒烯反应形成化学计量为1：2的分子复合物。
- TBB在 Pd(Ph3)4 催化剂存在下，与全氟链烯基锌试剂反应，得到新型三官能团单体1,3,5-三(α, β, β-三氟乙烯基)苯。
hcodes
Hazard Classifications
Aquatic Chronic 4
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Guojie Liu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3054-3058 (2009-09-08)
Cyanide (CN) is a powerful poison and rapidly toxic agent. Because of its wide availability and high toxicity, quantification of CN in blood and urine is frequently required in clinical and forensic practice. We present a sensitive and less time
Lawrence A Ford et al.
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
Kakali Datta et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 66-70 (2005-11-01)
By UV-vis spectrophotometric method it has been shown that 1,3,5-tribromobenzene (TBB) forms molecular complexes of 1:2 stoichiometry with [60]- and [70]fullerenes. An isosbestic point could be detected in case of the [70]fullerene complex. The formation constant of the [60]fullerene complex
Y Suzuki et al.
Nucleic acids symposium series, (44)(44), 125-126 (2003-08-09)
We have designed a new type of a DNA dendrimer which has rigid branched structure. The branching molecule was prepared from 1,3,5-tribromobenzene. The dendrimer unit, in which three oligonucleotide-chains, two molecules of T15 and one molecule of A15, linked to
S Kage et al.
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.
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