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Merck
CN

140066

1,3,5-三溴苯

98%

别名:

1,3,5-三溴苯

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关于此项目

经验公式(希尔记法):
C6H3Br3
化学文摘社编号:
分子量:
314.80
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-947-3
Beilstein/REAXYS Number:
1858917
MDL number:
Assay:
98%
Form:
powder
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Quality Level

assay

98%

form

powder

bp

271 °C (lit.)

mp

117-121 °C (lit.)

functional group

bromo

SMILES string

Brc1cc(Br)cc(Br)c1

InChI

1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H

InChI key

YWDUZLFWHVQCHY-UHFFFAOYSA-N

General description

  • 1,3,5-三溴苯(TBB)作为衍生化步骤的内标,用于通过气相色谱-质谱法测定人血浆和尿液中的氰化物
  • TBB与[60]-和[70]富勒烯反应形成化学计量为1:2的分子复合物
  • TBB在 Pd(Ph3)4 催化剂存在下,与全氟链烯基锌试剂反应,得到新型三官能团单体1,3,5-三(α, β, β-三氟乙烯基)苯


hcodes

Hazard Classifications

Aquatic Chronic 4

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Guojie Liu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3054-3058 (2009-09-08)
Cyanide (CN) is a powerful poison and rapidly toxic agent. Because of its wide availability and high toxicity, quantification of CN in blood and urine is frequently required in clinical and forensic practice. We present a sensitive and less time
Lawrence A Ford et al.
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
S Kage et al.
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.



全球贸易项目编号

货号GTIN
140066-100G04061838733146
140066-25G04061838733153